N-p-Toluenesulfonyliminoquinolinium Ylide

Base Information

• Chemical Name: N-p-Toluenesulfonyliminoquinolinium Ylide
• CAS No.: 30416-54-7
• Molecular Formula: C₁₆H₁₄N₂O₂S
• Molecular Weight: 298.365
• Mol file: 30416-54-7.mol

Synonyms:N-p-Toluenesulfonyliminoquinolinium Ylide

Chemical Property of N-p-Toluenesulfonyliminoquinolinium Ylide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-p-Toluenesulfonyliminoquinolinium Ylide

There total 3 articles about N-p-Toluenesulfonyliminoquinolinium Ylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

N-amino mesitylenesulfonate salt of quinoline (39996-55-9) + p-toluenesulfonyl chloride (98-59-9) → N-p-Toluenesulfonyliminoquinolinium Ylide (30416-54-7)

Guidance literature:

With potassium carbonate; In dichloromethane; for 12h;

Reference yield: 60.0%

quinoline (91-22-5) + 4-methyl-N-[(E)-phenyl-λ3-iodanylidene]benzenesulfonamide (55962-05-5) → N-p-Toluenesulfonyliminoquinolinium Ylide (30416-54-7)

Guidance literature:

With 4 A molecular sieve; [meso-tetrakis(p-tolyl)porphyrinato]ruthenium(II); In dichloromethane; at 30 ℃;

DOI:10.1055/s-2007-966048

Reference yield: 40.0%

quinoline (91-22-5) + [N-(p-tolylsulfonyl)imino]phenyliodinane (55962-05-5) → N-p-Toluenesulfonyliminoquinolinium Ylide (30416-54-7)

Guidance literature:

With 5A molecular sieve; copper(II) bis(trifluoromethanesulfonate); In acetonitrile; at 20 ℃; for 12h;

DOI:10.1016/S0040-4039(03)00939-0

upstream raw materials:

N-amino mesitylenesulfonate salt of quinoline

p-toluenesulfonyl chloride

quinoline

[N-(p-tolylsulfonyl)imino]phenyliodinane

Downstream raw materials:

2-phenylpyrazolo<1,5-a>quinoline

ethyl 2-phenylpyrazolo[1,5-a]quinoline-3-carboxylate

3-(4-Nitro-phenyl)-pyrazolo[1,5-a]quinoline

Refernces

• 1、 Jain, Suman L.,Sharma, Vishal B.,Sain, Bir. "Copper-catalyzed imination of pyridines using PhI=NTs as nitrene precursor". . p. 4385 - 4387. Retrieved 2003.