[N-(p-Toluenesulfonyl)imino]phenyliodinane

Base Information

• Chemical Name: [N-(p-Toluenesulfonyl)imino]phenyliodinane
• CAS No.: 55962-05-5
• Molecular Formula: C13H12INO2S
• Molecular Weight: 373.214
• Mol file: 55962-05-5.mol

Synonyms:[N-(p-Toluenesulfonyl)imino]phenyliodinane;[N-(p-tolylsulfonyl)imino]phenyliodinane

Chemical Property of [N-(p-Toluenesulfonyl)imino]phenyliodinane

Chemical Property:

• Melting Point: 104.0-105.0 °C (decomp)
• PSA: 54.88000
• LogP: 4.78860

Purity/Quality:

95% ^*data from raw suppliers

[N-(p-Toluenesulfonyl)imino]phenyliodinane 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [N-(p-Toluenesulfonyl)imino]phenyliodinane

There total 7 articles about [N-(p-Toluenesulfonyl)imino]phenyliodinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + toluene-4-sulfonamide (70-55-3) → [N-(p-tolylsulfonyl)imino]phenyliodinane (55962-05-5)

Guidance literature:

Inert atmosphere;

DOI:10.1021/acs.orglett.7b02922

Reference yield: 78.0%

toluene-4-sulfonamide (70-55-3) + iodobenzene dimethoxide (85083-59-6) → [N-(p-tolylsulfonyl)imino]phenyliodinane (55962-05-5)

Guidance literature:

In methanol;

DOI:10.1016/S0040-4039(00)61740-9

Reference yield: 66.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + toluene-4-sulfonamide (70-55-3) → 4-methyl-N-[(E)-phenyl-λ3-iodanylidene]benzenesulfonamide (55962-05-5)

Guidance literature:

With potassium hydroxide; In methanol; at 8 - 20 ℃; for 3h;

upstream raw materials:

[bis(acetoxy)iodo]benzene

toluene-4-sulfonamide

iodobenzene dimethoxide

iodosylbenzene

Downstream raw materials:

2-(4-methoxyphenyl)-1-tosylaziridine

iodobenzene

toluene-4-sulfonamide

N-(p-toluenesulfonyl)-2,2-diphenylaziridine

Refernces

• 1、 -. "Method for preparing azabicyclic compounds". Paragraph 0099-0100; 0102. . Retrieved 2021/11/14.
• 2、 Biletskyi, Bohdan,Kong, Lingyu,Tenaglia, Alphonse,Clavier, Hervé. "Cobalt-Catalyzed Hydroalkynylation of Vinylaziridines". supporting information. p. 2578 - 2585. Retrieved 2021/03/18.