triethylene glycol monobutyl ether tosylate

Base Information

• Chemical Name: triethylene glycol monobutyl ether tosylate
• CAS No.: 117783-11-6
• Molecular Formula: C₁₇H₂₈O₆S
• Molecular Weight: 360.472
• Mol file: 117783-11-6.mol

Synonyms:triethylene glycol monobutyl ether tosylate

Chemical Property of triethylene glycol monobutyl ether tosylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of triethylene glycol monobutyl ether tosylate

There total 1 articles about triethylene glycol monobutyl ether tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triethyleneglycol monobutyl ether (143-22-6,9004-77-7) + p-toluenesulfonyl chloride (98-59-9) → triethylene glycol monobutyl ether tosylate (117783-11-6)

Guidance literature:

triethyleneglycol monobutyl ether; p-toluenesulfonyl chloride; With dmap; In dichloromethane; at 20 ℃;

With triethylamine; In dichloromethane; at 20 ℃;

DOI:10.1021/jo102358d

Reference yield: 59.0%

1,1,3,3,5,5-hexakis(4-(hydroxymethyl)phenoxy)cyclotriphosphazene (49864-98-4) + triethylene glycol monobutyl ether tosylate (117783-11-6) → hexakiscyclophosphazene

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 48h; Heating;

Reference yield:

triethylene glycol monobutyl ether tosylate (117783-11-6) → 2-(2-(2-butoxyethoxy)ethoxy)ethanamine (85030-57-5)

Guidance literature:

Multi-step reaction with 2 steps

1: N,N-dimethyl-formamide / 18 h / 80 °C

2: hydrazine hydrate / ethanol / 3 h / 76 °C

With hydrazine hydrate; In ethanol; N,N-dimethyl-formamide; 2: Gabriel's dephthaloylation;

DOI:10.1021/jo102358d

upstream raw materials:

triethyleneglycol monobutyl ether

p-toluenesulfonyl chloride

Downstream raw materials:

2-(2-(2-butoxyethoxy)ethoxy)ethanamine

Refernces

• 1、 Corda, Luciana,Delogu, Giovanna,Maccioni, Antonio,Maccioni, Elias,Podda, Gianni. "SYNTHESIS OF NEW CYCLOPHOSPHAZENIC POLYPODANDS WITH N,N-BISAMINE SUBUNITS AND THEIR COMPARISON, AS PHASE-TRANSFER CATALYSTS, WITH OTHER PODANDS". . p. 491 - 496. Retrieved 2007/10/02.