Triethylene glycol monobutyl ether

Base Information

• Chemical Name: Triethylene glycol monobutyl ether
• CAS No.: 143-22-6
• Molecular Formula: C10H22O4
• Molecular Weight: 206.282
• Hs Code.: 2909.49
• European Community (EC) Number: 205-592-6
• ICSC Number: 0965
• NSC Number: 164915
• UNII: OC116GRO69
• DSSTox Substance ID: DTXSID7021520
• Nikkaji Number: J52.422K
• Wikidata: Q1815673
• RXCUI: 1424669
• ChEMBL ID: CHEMBL3184092
• Mol file: 143-22-6.mol

Synonyms:TRIETHYLENE GLYCOL MONOBUTYL ETHER;143-22-6;Butoxytriglycol;Butoxytriethylene glycol;Dowanol tbat;2-[2-(2-Butoxyethoxy)ethoxy]ethanol;Triglycol monobutyl ether;Triethylene glycol n-butyl ether;Triethylene glycol butyl ether;Ethanol, 2-[2-(2-butoxyethoxy)ethoxy]-;Butyltriglycol;Triethylene glycol mono-n-butyl ether;2-[2-(2-butoxyethoxy)ethoxy]ethan-1-ol;triethyleneglycolmonobutylether;3,6,9-Trioxa-1-tridecanol;2-(2-(2-Butoxyethoxy)ethoxy)ethanol;NSC 164915;Triethyleneglycol monobutyl ether;HSDB 5645;EINECS 205-592-6;BRN 1750600;UNII-OC116GRO69;3,6,9-Trioxatridecan-1-ol;Ethanol, 2-(2-(2-butoxyethoxy)ethoxy)-;AI3-30236;OC116GRO69;DTXSID7021520;NSC-164915;EC 205-592-6;DTXCID701520;CAS-143-22-6;Butoxytriglykol;Butyl Triglycol;TGBE;C(COCCCC)OCCOCCO;BUTETH-3;3,9-Trioxatridecan-1-ol;BUTETH-3 [INCI];PEG-3 BUTYL ETHER;SCHEMBL15523;WLN: Q2O2O2O4;triethyleneglycol monobutylether;CHEMBL3184092;Triethyleneglycol, monobutylether;UNII-T1J4684X95;Tox21_201885;Tox21_302836;MFCD00020606;NSC164915;AKOS024390783;T1J4684X95;2-(2-(2-butoxyethoxy)-ethoxy)-ethanol;NCGC00164337-01;NCGC00164337-02;NCGC00256567-01;NCGC00259434-01;BS-42318;LS-66524;3,6,9-TRIOXA-1-TRIDECANOL [HSDB];CS-0196787;FT-0623339;T0915;E82324;EN300-132557;J-007775;Q1815673;Triethylene glycol monobutyl ether, technical, ~70% (GC)

Chemical Property of Triethylene glycol monobutyl ether

Chemical Property:

• Appearance/Colour: colourless to faintly yellow liquid
• Vapor Pressure: 0.000537mmHg at 25°C
• Melting Point: -48 °C
• Refractive Index: 1.441
• Boiling Point: 278 °C at 760 mmHg
• PKA: 14.36±0.10(Predicted)
• Flash Point: 127.9 °C
• PSA: 47.92000
• Density: 0.981 g/cm³
• LogP: 0.82860
• Water Solubility.: It is soluble in water.
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 11
• Exact Mass: 206.15180918
• Heavy Atom Count: 14
• Complexity: 98.1

Purity/Quality:

99% ^*data from raw suppliers

Triethylene Glycol Monobutyl Ether >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/38-41
• Safety Statements: 26-36/37/39-46-39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Solvents -> Glycol Ethers (E Series)
• Canonical SMILES: CCCCOCCOCCOCCO
• Inhalation Risk: A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20 °C.
• Effects of Short Term Exposure: The substance is irritating to the eyes. The substance is mildly irritating to the skin.
• Effects of Long Term Exposure: The substance defats the skin, which may cause dryness or cracking.
• Uses: Plasticizer, intermediate. Triethylene glycol monobutyl ether, glycol ether a highly effective carrier solvent for textile dye processes. With superior surface tension characteristics, water solubility and solvency for oils, it has potential for use in household, institutional, industrial and special-purpose cleaners. The coupling ability of this product enhances performance and improves shelf stability of cleaning products. It is also used as an active solvent for solvent-based coatings, dye carrier for textile dye processes, coupling agent and solvent in household and industrial cleaners, paint and floor polish strippers, hard surface cleaners, and disinfectants, chemical process solvent and intermediate for ester production used as solvents, surfactants and plasticizers, coupling agent for resins and dyes in water-based printing ink, component of high-boiling hydraulic brake fluids. Triethylene glycol monobutyl ether (TEGMBE) can be used as a solvent:In the synthesis of superparamagnetic iron oxide nanoparticles by thermal decomposition method.in the removal of CO2 due to its solubilize CO2.It can also be used as a reactant in the preparation of polyether adducts of bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)barium.

Technology Process of Triethylene glycol monobutyl ether

There total 4 articles about Triethylene glycol monobutyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

→ triethyleneglycol monobutyl ether (143-22-6,9004-77-7)

Guidance literature:

With pyridinium p-toluenesulfonate; In methanol; at 0 - 20 ℃; for 16h;

Reference yield:

Tetraethylene glycol (112-60-7) + ethylene glycol (107-21-1) + butyraldehyde (123-72-8) + diethylene glycol (111-46-6) + 2,2'-[1,2-ethanediylbis(oxy)]bisethanol (112-27-6) → 2-propyl-1,3-dioxolane (3390-13-4) + 2-Butoxyethanol (111-76-2,9004-77-7) + Diethylene glycol monobutyl ether (112-34-5,9004-77-7) + triethyleneglycol monobutyl ether (143-22-6,9004-77-7) + tetraethylene glycol monobutyl ether (1559-34-8,9004-77-7) + butan-1-ol (71-36-3)

Guidance literature:

With hydrogen; palladium 10% on activated carbon; at 180 ℃; for 2h; under 51716.2 Torr;

Reference yield:

oxirane (75-21-8,99932-75-9) + butan-1-ol (71-36-3) → 2-Butoxyethanol (111-76-2,9004-77-7) + Diethylene glycol monobutyl ether (112-34-5,9004-77-7) + triethyleneglycol monobutyl ether (143-22-6,9004-77-7)

Guidance literature:

2,4,6-trimethyl-pyridine; at 160 ℃; for 2.5h; under 2311.54 - 3345.86 Torr; Product distribution / selectivity; Inert atmosphere;

upstream raw materials:

oxirane

butan-1-ol

Tetraethylene glycol

ethylene glycol

Downstream raw materials:

2-(2-(2-butoxyethoxy)ethoxy)ethanamine

tetraethylene glycol dibutyl ether

3-Benzyloxypropylenbis(3,6,9-trioxatridecanoat)

triethylene glycol monobutyl ether tosylate

Refernces

• 1、 -. "POLYOL ETHERS AND PROCESS FOR MAKING THEM". Page/Page column 7. . Retrieved 2010/03/31.
• 2、 -. "Combinatorial synthesis of PEG oligomer libraries". Page/Page column 9. . Retrieved 2010/02/15.