methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

Base Information

Chemical Name:methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose
CAS No.:848477-39-4
Molecular Formula:C₁₈H₂₃NO₆
Molecular Weight:349.384
Hs Code.:

Synonyms:methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

Suppliers and Price of methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

There total 4 articles about methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 651735-90-9
methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-glucopyranoside

: 848477-39-4
methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 - 20 ℃;
DOI:10.1016/j.tetasy.2004.11.049

Reference yield:

: 128657-58-9
methyl 2-amino-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside

: 848477-39-4
methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / potassium carbonate / acetonitrile / Heating

2: 82 percent / oxalyl chloride; dimethyl sulfoxide; triethylamine / CH₂Cl₂ / -78 - 20 °C

With oxalyl dichloride; potassium carbonate; dimethyl sulfoxide; triethylamine; In dichloromethane; acetonitrile; 2: Swern oxidation;
DOI:10.1016/j.tetasy.2004.11.049

Reference yield:

: 651736-08-2
methyl 4,6-O-benzylidene-α-D-arabino-hexopyranoside-2-ulose Z-oxime

: 848477-39-4
methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose

Guidance literature:: Multi-step reaction with 3 steps

1: 22 percent / lithium aluminium hydride; sulfuric acid / tetrahydrofuran / 5 h / 20 °C

2: 91 percent / potassium carbonate / acetonitrile / Heating

3: 82 percent / oxalyl chloride; dimethyl sulfoxide; triethylamine / CH₂Cl₂ / -78 - 20 °C

With lithium aluminium tetrahydride; oxalyl dichloride; sulfuric acid; potassium carbonate; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; acetonitrile; 3: Swern oxidation;
DOI:10.1016/j.tetasy.2004.11.049