μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}

Base Information

Chemical Name:μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}
CAS No.:111800-75-0
Molecular Formula:C₃₀H₂₇B₃Co₂
Molecular Weight:537.964
Hs Code.:

Synonyms:μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}

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Chemical Property of μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}

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Technology Process of μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}

There total 4 articles about μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 10170-69-1
dimanganese decacarbonyl

: di-μ-carbonyl-bis{carbonyl(η5-1-phenylborole)cobalt}(Co-Co)

: 111800-75-0
μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}

: 87871-00-9
μ-{η5-(1-phenylborole)}-bis(tricarbonylmanganese)

: 111825-59-3
μ-{η5-(1-phenylborole)}-{η5-(1-phenylborole)cobalt}(tricarbonylmanganese)

: 111800-78-3
μ-{η5:η5-(trans-1,1'-diphenyl-2,2'-bisborolyl)}-bis(dicarbonylcobalt)(Co-Co)

Guidance literature:: In 1,3,5-trimethyl-benzene; refluxed for 8 h under N2; evapd., products were sepd. by chromy. on Al2O3 (7% H2O, eluent pentane followed by pentane-CH2Cl2), (C4H4BPh)Co(C4H4BPh)Mn(CO)3 was recrystd. from hexane; elem. anal. for the latter complex;
DOI:10.1016/0022-328X(87)80343-1

Reference yield: 37.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 111800-81-8
Na-bis(borole)cobaltate

: 111800-75-0
μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}

: 111825-63-9
bis{μ-{η5-(1-phenylborole)}-{η5-(1-phenylborole)}cobalt}ruthenium

Guidance literature:: With zinc; In tetrahydrofuran; ethanol; Zn-dust was added to a soln. of RuCl3*3H2O in 10:1 (v/v) THF-ethanol, mixt. was vigorously stirred for 12 h under N2, soln. was decanted and added dropwise at -80°C under N2 to a soln. of Co-complex in THF, mixt. was stirred for 3 h at room temp.; evapd., residue was chromd. over Al2O3 (7% H2O, pentane-CH2Cl2), quadruple-decker complex was recrystd. from CH2Cl2-pentane at -60°C; elem. anal.;
DOI:10.1016/0022-328X(87)80343-1

Reference yield:

: di-μ-carbonyl-bis{carbonyl(η5-1-phenylborole)cobalt}(Co-Co)

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 12078-25-0,12078-23-8
dicarbonylcyclopentadienylcobalt

: {C5H5Co(η5-C4H4BPh)}

: 111800-75-0
μ-{η5-(1-phenylborole)}-bis{η5-(1-phenylborole)cobalt}

Guidance literature:: In not given; direct pyrolysis in the presence of cyclopentadiene; CpCo(CO)2 was identified by its IR spectrum;
DOI:10.1016/0022-328X(87)80343-1