bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

Base Information

Chemical Name:bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester
CAS No.:1154062-17-5
Molecular Formula:C₂₈H₃₄O₅
Molecular Weight:450.575
Hs Code.:

Synonyms:bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

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Chemical Property of bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

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Technology Process of bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

There total 2 articles about bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1154062-14-2
propenoic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

: 1154062-17-5
bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

Guidance literature:: propenoic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester; With dimethyl aluminium chloride; In tetrahydrofuran; at -80 ℃; for 0.0166667h; Inert atmosphere;

cyclopenta-1,3-diene; In tetrahydrofuran; at -80 - -50 ℃; for 2.5h; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.02.004

Reference yield:

: 1154062-14-2
propenoic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

: 1154062-17-5
bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

Guidance literature:: propenoic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester; With magnesium bromide ethyl etherate; In dichloromethane; at -80 ℃; for 0.0166667h; Inert atmosphere;

cyclopenta-1,3-diene; In dichloromethane; at -80 - -50 ℃; for 2.5h; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.02.004

Reference yield:

: 1154062-17-5
bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester

: 120-74-1,934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7
(1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

Guidance literature:: bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S)-1,2-bis(2-methoxyphenyl)-2-(2-methylpropoxy)ethyl ester; With lithium hydroxide; water; In 1,2-dimethoxyethane; for 24h; Reflux;

With water; sodium hydrogencarbonate;

With hydrogenchloride; In water; pH=2; optical yield given as %ee;
DOI:10.1016/j.tetasy.2009.02.004