2-Phenylethyl methacrylate

Base Information

• Chemical Name: 2-Phenylethyl methacrylate
• CAS No.: 3683-12-3
• Molecular Formula: C12H14 O2
• Molecular Weight: 190.242
• Hs Code.: 2916140000
• European Community (EC) Number: 222-969-0
• UNII: 5VLG348MDF
• DSSTox Substance ID: DTXSID7063134
• Nikkaji Number: J205.594E
• Wikidata: Q72501832
• Mol file: 3683-12-3.mol

Synonyms:2-Phenylethyl methacrylate;3683-12-3;Phenethyl methacrylate;2-phenylethyl 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-, 2-phenylethyl ester;Phenylethyl methacrylate;Phenylethyl 2-methyl-2-propenoate;5VLG348MDF;beta-Phenylethyl methacrylate;.beta.-Phenylethyl methacrylate;Methacrylic acid, phenethyl ester;2-Phenylethyl Methacrylate (stabilized with HQ);beta-Phenylethyl 2-methylpropenate;EINECS 222-969-0;BRN 2329237;AI3-36654;2-phenylethylmethacrylate;Methacrylate 2-phenylethyl;UNII-5VLG348MDF;SCHEMBL42893;DTXSID7063134;2-Phenylethyl 2-methylacrylate #;MFCD00038232;2-Phenylethyl methacrylate,min. 92%;AKOS006343929;LS-123709;P2714;Methacrylic acid, phenethyl ester (7CI,8CI);F88621;3-06-00-01710 (Beilstein Handbook Reference);2-Phenylethyl Methacrylate, >/=98%,stabilized with HQ

Chemical Property of 2-Phenylethyl methacrylate

Chemical Property:

• Vapor Pressure: 0.00248mmHg at 25°C
• Melting Point: 119～120℃/11mm
• Refractive Index: 1.4970 (estimate)
• Boiling Point: 287.4 °C at 760 mmHg
• Flash Point: 157.5 °C
• PSA: 26.30000
• Density: 1.019 g/cm³
• LogP: 2.34840
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 190.099379685
• Heavy Atom Count: 14
• Complexity: 202

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Phenylethyl Methacrylate (stabilized with HQ) ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCC1=CC=CC=C1

Technology Process of 2-Phenylethyl methacrylate

There total 5 articles about 2-Phenylethyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.2%

2-phenylethanol (60-12-8) + Methacryloyl chloride (920-46-7,26937-45-1) → 2-phenylethyl methacrylate (3683-12-3,28825-60-7)

Guidance literature:

2-phenylethanol; With triethylamine; In dichloromethane; for 0.0833333h; Cooling with ice;

Methacryloyl chloride; In dichloromethane; at 0 - 20 ℃;

DOI:10.1111/php.12038

Reference yield:

2-phenylethanol (60-12-8) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-phenylethyl methacrylate (3683-12-3,28825-60-7)

Guidance literature:

With sulfuric acid; hydroquinone; benzene; at 130 - 136 ℃; Erhitzen unter Abdestillieren des entstehenden Methanols;

Reference yield:

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 2-phenylethanol (60-12-8) → 2-phenylethyl methacrylate (3683-12-3,28825-60-7)

Guidance literature:

With toluene-4-sulfonic acid; hydroquinone; In benzene; for 9h; Yield given; Heating;

upstream raw materials:

2-phenylethyl 2-hydroxy-2-methylpropionate

2-phenylethanol

methacrylic acid methyl ester

poly(methacrylic acid)

Refernces

• 1、 Tokuyasu, Takahiro,Kunikawa, Shigeki,McCullough, Kevin J.,Masuyama, Araki,Nojima, Masatomo. "Synthesis of cyclic peroxides by chemo- and regioselective peroxidation of dienes with Co(II)/O2/Et3SiH". . p. 251 - 260. Retrieved 2007/10/03.