Methyl N-(phenylmethylidene)-beta-alaninate

Base Information

Chemical Name:Methyl N-(phenylmethylidene)-beta-alaninate
CAS No.:138495-06-4
Molecular Formula:C₁₁H₁₃NO₂
Molecular Weight:191.23
Hs Code.:
DSSTox Substance ID:DTXSID401231727
Nikkaji Number:J1.851.965H,J2.115.592F

Synonyms:Methyl N-(phenylmethylidene)-.beta.-alaninate;138495-06-4;DLZXVOXSALWUGE-FMIVXFBMSA-N;DTXSID401231727;3-(Benzylideneamino)propanoic acid methyl ester;[N(E)]-N-(Phenylmethylene)-beta-alanine methyl ester;3-[[(E)-Benzylidene]amino]propionic acid methyl ester

Suppliers and Price of Methyl N-(phenylmethylidene)-beta-alaninate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Methyl N-(phenylmethylidene)-beta-alaninate

Chemical Property:

XLogP3:1.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:191.094628657
Heavy Atom Count:14
Complexity:196

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)CCN=CC1=CC=CC=C1

Technology Process of Methyl N-(phenylmethylidene)-beta-alaninate

There total 1 articles about Methyl N-(phenylmethylidene)-beta-alaninate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-52-7
benzaldehyde

: 4138-35-6
methyl 3-aminopropanoate

: 138495-06-4
N-benzyliden-β-alanine methyl ester

Guidance literature:: With magnesium sulfate; In dichloromethane; at 20 ℃;
DOI:10.1021/jo0488917

Reference yield: 64.0%

: 40052-11-7
2-bromo-3-methyl-but-2-enoyl chloride

: 138495-06-4
N-benzyliden-β-alanine methyl ester

: 3-(3-bromo-2-oxo-6-phenyl-4-methyl-5,6-dihydropyridin-1-yl)-propionic acid methyl ester

Guidance literature:: With triethylamine; In dichloromethane; Heating;
DOI:10.1016/j.tet.2004.04.021

Reference yield:

: 673-32-5
1-Phenylprop-1-yne

: 97-94-9
triethyl borane

: 138495-06-4
N-benzyliden-β-alanine methyl ester

: 3-((E)-2-Methyl-1,3-diphenyl-allylamino)-propionic acid methyl ester

: 3-((Z)-3-Methyl-1,2-diphenyl-pent-2-enylamino)-propionic acid methyl ester

: 3-((E)-2-Methyl-1,3-diphenyl-pent-2-enylamino)-propionic acid methyl ester

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; tricyclopentylphosphine; In methanol; acetic acid methyl ester; at 50 ℃; for 16h;
DOI:10.1002/anie.200390349