Mesitylenesulfonic benzylidenehydrazide

Base Information

• Chemical Name: Mesitylenesulfonic benzylidenehydrazide
• CAS No.: 16182-18-6
• Molecular Formula: C₁₆H₁₈N₂O₂S
• Molecular Weight: 302.397
• European Community (EC) Number: 660-579-6
• Mol file: 16182-18-6.mol

Synonyms:AKOS024339727;MESITYLENESULFONIC BENZYLIDENEHYDRAZIDE

Chemical Property of Mesitylenesulfonic benzylidenehydrazide

Chemical Property:

• XLogP3: 3.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 302.10889899
• Heavy Atom Count: 21
• Complexity: 437

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)S(=O)(=O)NN=CC2=CC=CC=C2)C
• Isomeric SMILES: CC1=CC(=C(C(=C1)C)S(=O)(=O)N/N=C\C2=CC=CC=C2)C

Technology Process of Mesitylenesulfonic benzylidenehydrazide

There total 2 articles about Mesitylenesulfonic benzylidenehydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

2,4,6-trimethylbenzenesulfonohydrazide (16182-15-3) + benzaldehyde (100-52-7) → benzaldehyde 2,4,6-trimethylbenzenesulfonyl hydrazone (16182-18-6)

Guidance literature:

In ethanol; for 24h; Heating;

Reference yield:

→ benzaldehyde 2,4,6-trimethylbenzenesulfonyl hydrazone (16182-18-6)

Guidance literature:

Benzaldehyd, /BRN= 118380/;

Reference yield: 95.0%

2-(N,N-dimethylamino)-2-phenylacetonitrile (827-36-1) + benzaldehyde 2,4,6-trimethylbenzenesulfonyl hydrazone (16182-18-6) → α-(N,N-dimethylamino)-α,α'-diphenylazine (87531-32-6)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; 1.) -78 deg C, 1 h; 2.) RT;

DOI:10.1246/cl.1983.993

upstream raw materials:

2,4,6-trimethylbenzenesulfonohydrazide

benzaldehyde

Downstream raw materials:

α-(N,N-dimethylamino)-α,α'-diphenylazine

phenyldiazomethane

3,5-dinitrobenzoate of benzyl alcohol

2-phenylcyclooctan-1-one