2-Nitro-1-phenyliminoguanidine

Base Information

• Chemical Name: 2-Nitro-1-phenyliminoguanidine
• CAS No.: 1924-85-2
• Molecular Formula: C7H8N5O2+
• Molecular Weight: 193.165
• NSC Number: 206187
• DSSTox Substance ID: DTXSID40430665
• Mol file: 1924-85-2.mol

Synonyms:1924-85-2;ST51000184;DTXSID40430665;NSC206187;AKOS024366579;NSC-206187

Chemical Property of 2-Nitro-1-phenyliminoguanidine

Chemical Property:

• XLogP3: 1.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 193.05997448
• Heavy Atom Count: 14
• Complexity: 251

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N=NC(=N[N+](=O)[O-])N
• Isomeric SMILES: C1=CC=C(C=C1)N=N/C(=N/[N+](=O)[O-])/N

Technology Process of 2-Nitro-1-phenyliminoguanidine

There total 4 articles about 2-Nitro-1-phenyliminoguanidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2-phenylhydrazino-N2-nitroformamidine (100524-26-3) → phenylazo-N2-nitroformamidine (1924-85-2)

Guidance literature:

With bromine; In water; at 0 - 5 ℃; for 0.333333h;

Reference yield:

phenylhydrazine (100-63-0) → phenylazo-N2-nitroformamidine (1924-85-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / H₂O

2: 94 percent / Br₂ / H₂O / 0.33 h / 0 - 5 °C

With bromine; In water;

Reference yield:

phenylhydrazine hydrochloride (59-88-1) → phenylazo-N2-nitroformamidine (1924-85-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 78 percent / KOH / H₂O / 3 h / 50 - 60 °C

2: 92 percent / bromine / H₂O / 0.25 h / 0 - 5 °C

With potassium hydroxide; bromine; In water;

DOI:10.1007/BF00961362

upstream raw materials:

N-anilino-N'-nitro-guanidine

2-phenylhydrazino-N²-nitroformamidine

phenylhydrazine

phenylhydrazine hydrochloride

Downstream raw materials:

phenyl-ONN-azoxy-N²-nitroformamidine

3-nitrophenylazo-N²-nitroformamidine

2-nitrophenylazo-N²-nitroformamidine

(3-nitrophenyl-ONN-azoxy)-N²-nitroformamidine