(C₅Me₅)2Sm(CH₂C₆H₅)(THF)

Base Information

Chemical Name:(C₅Me₅)2Sm(CH₂C₆H₅)(THF)
CAS No.:115731-51-6
Molecular Formula:C₃₁H₄₅OSm
Molecular Weight:584.058
Hs Code.:

(C<sub>5</sub>Me<sub>5</sub>)2Sm(CH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>)(THF)

Synonyms:(C₅Me₅)2Sm(CH₂C₆H₅)(THF)

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Chemical Property of (C₅Me₅)2Sm(CH₂C₆H₅)(THF)

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Technology Process of (C₅Me₅)2Sm(CH₂C₆H₅)(THF)

There total 3 articles about (C₅Me₅)2Sm(CH₂C₆H₅)(THF) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 84751-30-4
[(pentamethylcyclopentadienyl)2Sm(μ-H)]2

: 108-88-3,15644-74-3,16713-13-6
toluene

: 110-83-8
cyclohexene

: 115731-51-6
(C₅Me₅)2Sm(CH₂C₆H₅)(THF)

Guidance literature:: With THF; In hexane; toluene; byproducts: cyclohexane; addn. of cyclohexene to a soln. of Sm-compd., stirring, removal of solvent, extractn. with hexane, addn. of THF; removal of solvent, elem. anal.;

Reference yield: 74.0%

: 115731-48-1
(C₅Me₅)2SmMe(THF)

: 108-88-3,15644-74-3,16713-13-6
toluene

: 115731-51-6
(C₅Me₅)2Sm(CH₂C₆H₅)(THF)

: 34557-54-5,27936-85-2
methane

Guidance literature:: In toluene; in a glove box under N2 (C5Me5)2SmMe(THF) was dissolved in toluene, stirred for 5 days, removal of the solvent by rotatory evapn.;; addn. of THF and solvent removal; (1)H-NMR-spectroscopy;;
DOI:10.1021/ja00227a023

Reference yield:

: 115731-48-1
(C₅Me₅)2SmMe(THF)

: 1076-43-3
benzene-d6

: 108-88-3,15644-74-3,16713-13-6
toluene

: 115731-51-6
(C₅Me₅)2Sm(CH₂C₆H₅)(THF)

: 115731-50-5
(C₅Me₅)2Sm(C₆D₅)(THF)

Guidance literature:: In benzene-d6; toluene; under N2 with exclusion of air and water;; only small amts. of (C5Me5)2Sm(C6D5)(THF) formed after reaction time >1 day; monitored by (1)H-NMR-spectroscopy;;
DOI:10.1021/ja00227a023