(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide

Base Information

Chemical Name:(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide
CAS No.:885022-93-5
Molecular Formula:C₆₀H₇₃NO₅Si₂
Molecular Weight:944.414
Hs Code.:

Synonyms:(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide

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Chemical Property of (Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide

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Technology Process of (Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide

There total 10 articles about (Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 863544-74-5
(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-hydroxy-9-dodecenamide

: 65-85-0,8013-63-6
benzoic acid

: 885022-93-5
(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 16h;
DOI:10.1021/jm051226l

Reference yield:

: 885022-89-9
di-O-tert-butyldiphenylsilyl-(S)-tyrosinol

: 885022-93-5
(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide

Guidance literature:: Multi-step reaction with 3 steps

1.1: isobutyl chloroformate; N-methylmorpholine / acetonitrile / 1 h / -5 °C

1.2: 491 mg / acetonitrile / 1 h / 20 °C

2.1: 51 percent / p-toluenesulfonic acid hydrate; MeOH / 2.5 h / 25 °C

3.1: 50 percent / DCC; DMAP / CH₂Cl₂ / 16 h / 20 °C

With 4-methyl-morpholine; methanol; dmap; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; isobutyl chloroformate; In dichloromethane; acetonitrile;
DOI:10.1021/jm051226l

Reference yield:

: 863544-73-4
(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-[(tetrahydro-2H-pyran-2-yl)oxy]-9-dodecenamide

: 885022-93-5
(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-(benzoyloxy)-9-dodecenamide

Guidance literature:: Multi-step reaction with 2 steps

1: 51 percent / p-toluenesulfonic acid hydrate; MeOH / 2.5 h / 25 °C

2: 50 percent / DCC; DMAP / CH₂Cl₂ / 16 h / 20 °C

With methanol; dmap; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; In dichloromethane;
DOI:10.1021/jm051226l