3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium

Base Information

• Chemical Name: 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium
• CAS No.: 917598-24-4
• Molecular Formula: C₃₀H₄₀B₉ClP₂Ru
• Molecular Weight: 696.417
• Mol file: 917598-24-4.mol

Synonyms:3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium

Chemical Property of 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium

There total 3 articles about 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

3,3-bis(triphenylphosphine)-3-chloro-3-hydrido-3,1,2-closo-dicarbollylruthenium + 1,4-di(diphenylphosphino)-butane (7688-25-7) → 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium (917598-24-4)

Guidance literature:

In benzene; (Ar); stirring soln. of ruthenium compd. and phosphine deriv. in benzeneat room temp. for 72 h; evapn., chromy. (silica gel, benzene/hexane (1:1)), recrystn. (hexane/Ch2Cl2), NMR spectroscopy;

DOI:10.1007/s11172-006-0394-9

Reference yield: 80.0%

exo-chloro[1',4'-bis(diphenylphosphino)butane]-nido-[10-hydro-ortho-carborane-5,6,10-tris(hydrido)]ruthenium → 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium (917598-24-4)

Guidance literature:

In benzene; (Ar); upon storage in soln.;

DOI:10.1007/s11172-010-0217-x

Reference yield: 73.0%

chlorobis(triphenylphosphine)-exo-nido-[10-hydroorthocarborane-5,6,10-tris(hydro)]ruthenium(II) + 1,4-di(diphenylphosphino)-butane (7688-25-7) → 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium (917598-24-4)

Guidance literature:

In benzene; under Ar atm.; Ru complex added to soln. of phosphine in C6H6; mixt. stirred under gentle reflux for 1 h; solvent removed (vac.); residue chromd. on silica gel column (C6H6-hexane, 1:1 as eluent);

DOI:10.1007/s11172-006-0151-0

upstream raw materials:

1,4-di(diphenylphosphino)-butane

Downstream raw materials:

3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10

3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9

[3,3-(dppb)-3-Cl-closo-3,1,2-RuC₂B₉H₁₁]

3-Cl-3,3,7,8-(Ph2P(CH2)4P-μ-(C6H4-ortho)2)-closo-3,1,2-RuC2B9H9