3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10

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Chemical Name:3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10
CAS No.:1314905-87-7
Molecular Formula:C₃₀H₃₇B₉ClP₂Ru
Molecular Weight:693.393
Hs Code.:

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Chemical Property of 3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10

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Technology Process of 3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10

There total 4 articles about 3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: [3,3-(dppb)-3-Cl-closo-3,1,2-RuC₂B₉H₁₁]*0.3(n-C₇H₁₆)

: 1314905-87-7
3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10

Guidance literature:: In toluene; (Ar); stirred at 95°C for 7.5 h; evapd. (vac.), chromd. (silica gel, C6H6/n-hexane), recrystd. (CH2Cl2/n-hexane);
DOI:10.1021/ic200487w

Reference yield: 34.0%

: 56-23-5
tetrachloromethane

: 917598-24-4
3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium

: 1314905-87-7
3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10

: 1314905-88-8
3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9

: [3,3-(dppb)-3-Cl-closo-3,1,2-RuC₂B₉H₁₁]*0.3(n-C₇H₁₆)

Guidance literature:: With CCl₄; In benzene; (Ar); CCl4 added to a soln. of Ru complex in C6H6, stirred at room temp.for 15 min, refluxed for ca 4 h; cooled, evapd. (vac.), chromd. (silica gel, C6H6/n-hexane), recrystd. (CH2Cl2/petroleum ether, at 10°C for 12 h); elem. anal.;
DOI:10.1021/ic200487w

Reference yield: 12.0%

: 917598-24-4
3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium

: 1314905-87-7
3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10

: 1314905-89-9
3-Cl-3,3,7,8-(Ph2P(CH2)4P-μ-(C6H4-ortho)2)-closo-3,1,2-RuC2B9H9

Guidance literature:: In toluene; (Ar); gently refluxed for 5 h; evapd. (vac.), chromd. (silica gel, C6H6/n-hexane, C6H6), evapd., recrystd. (CH2Cl2/n-hexane); elem. anal.;
DOI:10.1021/ic200487w