3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9

Base Information

• Chemical Name: 3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9
• CAS No.: 1314905-88-8
• Molecular Formula: C₃₀H₃₆B₉Cl₂P₂Ru
• Molecular Weight: 727.838
• Mol file: 1314905-88-8.mol

Synonyms:

Chemical Property of 3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9

There total 2 articles about 3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

tetrachloromethane (56-23-5) + 3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10 (1314905-87-7) → 3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9 (1314905-88-8)

Guidance literature:

In tetrachloromethane; (Ar); refluxed gently for 20.5 h; evapd. (vac.), chromd. (silica gel, C6H6/n-hexane), evapd. (vac.), recrystd. (CH2Cl2/n-hexane); elem. anal.;

DOI:10.1021/ic200487w

Reference yield: 34.0%

tetrachloromethane (56-23-5) + 3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium (917598-24-4) → 3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10 (1314905-87-7) + 3,7-Cl2-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H9 (1314905-88-8) + [3,3-(dppb)-3-Cl-closo-3,1,2-RuC2B9H11]*0.3(n-C7H16)

Guidance literature:

With CCl₄; In benzene; (Ar); CCl4 added to a soln. of Ru complex in C6H6, stirred at room temp.for 15 min, refluxed for ca 4 h; cooled, evapd. (vac.), chromd. (silica gel, C6H6/n-hexane), recrystd. (CH2Cl2/petroleum ether, at 10°C for 12 h); elem. anal.;

DOI:10.1021/ic200487w

upstream raw materials:

tetrachloromethane

3-chloro-3,3-(1,4-diphenylphosphinobutane)-3-hydro-3,1,2-closo-dicarbollylruthenium

3-Cl-3,3,8-(Ph2P(CH2)4PPh-μ-(C6H4-ortho))-closo-3,1,2-RuC2B9H10