3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

Base Information

Chemical Name:3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone
CAS No.:202401-78-3
Molecular Formula:C₁₉H₂₆N₄O₄
Molecular Weight:374.44
Hs Code.:

Synonyms:3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

Suppliers and Price of 3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

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Technology Process of 3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

There total 2 articles about 3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 136668-01-4
2-amino-N-[2-(2-amino-2-methyl-propionylamino)-phenyl]-2-methyl-propionamide

: 5659-93-8
2,2-Dimethylmalonyl chloride

: 202401-78-3
3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

Guidance literature:: With triethylamine; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/jacs.8b00032

Reference yield:

: 401846-08-0
N,N’-(1,2-phenylene)bis(2-(1,3-dioxoisoindolin-2-yl)-2-methylpropanamide)

: 202401-78-3
3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

Guidance literature:: Multi-step reaction with 2 steps

1: hydrazine hydrate

2: triethylamine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

With hydrazine hydrate; triethylamine; In tetrahydrofuran;
DOI:10.1021/jacs.8b00032

Reference yield: 80.0%

: bis(acetylacetonate)nickel(II)

: 202401-78-3
3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone

: 865-48-5
sodium t-butanolate

: C₁₉H₂₂N₄NiO₄^(2-)*2Na⁽¹⁺⁾

Guidance literature:: 3,4,8,9-tetrahydro-3,3,6,6,9,-hexamethyl-1H-1,4,8,11-benzotetraazocyclotridecane-2,5,7,10 (6H, 11H) tetrone; sodium t-butanolate; In tetrahydrofuran; for 1h; Reflux;

bis(acetylacetonate)nickel(II); In tetrahydrofuran; for 5h;
DOI:10.1002/cssc.202000153