(5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride

Base Information

Chemical Name:(5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride
CAS No.:1174231-87-8
Molecular Formula:C₄₆H₂₈ClMnN₄
Molecular Weight:727.146
Hs Code.:

Synonyms:(5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride

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Chemical Property of (5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride

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Technology Process of (5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride

There total 2 articles about (5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 5,10,15-triphenyl-20-{4-[2-(trimethylsilyl)ethynyl]phenyl}porphyrin

: 1174231-87-8
(5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride

Guidance literature:: 5,10,15-triphenyl-20-{4-[2-(trimethylsilyl)ethynyl]phenyl}porphyrin; With manganese (II) acetate tetrahydrate; In N,N-dimethyl-formamide; Inert atmosphere; Reflux;

With sodium chloride; In dichloromethane; water; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1016/j.jorganchem.2009.02.020

Reference yield:

: 5-(4-[(trimethylsilyl)ethynyl]phenyl)-10,15,20-trisphenylporphyrin

: 6156-78-1
manganese (II) acetate tetrahydrate

: 7647-14-5
sodium chloride

: 34557-72-7,32195-55-4
(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

: 1174231-87-8
(5-(p-acetylenephenyl)-10,15,20-trisphenylporphyrin)manganese(III) chloride

Guidance literature:: In dichloromethane; water; N,N-dimethyl-formamide; (N2); Schlenk technique; Mn salt was added to soln. of porphyrin in DMF;stirred under reflux overnight; cooled to room temp.; ice-cooled soln. of NaCl was added; filtered; dissolved in CH2Cl2; satd. soln. of NaCl wa s added; stirred (room temp., 3 h); org. layer septd.; dried (MgSO4); concd. (vac.); chromd. (silica gel, hexane/CH2Cl2, 3/1, 5% MeOH); evapd.; dried (vac.);
DOI:10.1016/j.jorganchem.2009.02.020