S-phenyl 10-undecene thioate

Base Information

• Chemical Name: S-phenyl 10-undecene thioate
• CAS No.: 68117-63-5
• Molecular Formula: C₁₇H₂₄OS
• Molecular Weight: 276.443
• Mol file: 68117-63-5.mol

Synonyms:S-phenyl 10-undecene thioate

Chemical Property of S-phenyl 10-undecene thioate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-phenyl 10-undecene thioate

There total 2 articles about S-phenyl 10-undecene thioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

10-undecenoic acid (112-38-9) + diphenyldisulfane (882-33-7) → S-phenyl 10-undecene thioate (68117-63-5)

Guidance literature:

With triethylphosphine; for 1h; Ambient temperature; solvent is anh. benzene or diethyl ether;

DOI:10.1016/S0040-4039(00)85021-2

Reference yield: 92.0%

undec-10-enoyl chloride (38460-95-6) + thiophenol (108-98-5) → S-phenyl 10-undecene thioate (68117-63-5)

Guidance literature:

With triethylamine; In toluene; for 0.666667h;

DOI:10.1002/anie.200705768

Reference yield: 15.0%

3-(3-pyridinyl)propionaldehyde (1802-16-0) + S-phenyl 10-undecene thioate (68117-63-5) → (3RS,4RS)-3-non-8-enyl-4-(2-(3-pyridyl)ethyl)-oxetan-2-one (1359752-95-6) + (3RS,4SR)-3-non-8-enyl-4-(2-(3-pyridyl)ethyl)-oxetan-2-one (1359752-95-6)

Guidance literature:

S-phenyl 10-undecene thioate; With n-butyllithium; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 2.33333h; Inert atmosphere;

3-(3-pyridinyl)propionaldehyde; In tetrahydrofuran; hexane; at -78 - -5 ℃; Inert atmosphere;

DOI:10.1016/j.bmc.2011.07.047

upstream raw materials:

undec-10-enoyl chloride

thiophenol

10-undecenoic acid

diphenyldisulfane

Downstream raw materials:

Trimethyl-((E)-1-phenylsulfanyl-undeca-1,10-dienyloxy)-silane

1-dodecen-11-one

(3RS,4RS)-3-non-8-enyl-4-(2-(3-pyridyl)ethyl)-oxetan-2-one

(3RS,4SR)-3-non-8-enyl-4-(2-(3-pyridyl)ethyl)-oxetan-2-one