1-Benzoylpyren

Base Information

• Chemical Name: 1-Benzoylpyren
• CAS No.: 7376-03-6
• Molecular Formula: C₂₃H₁₄O
• Molecular Weight: 306.364
• Mol file: 7376-03-6.mol

Synonyms:phenylpyren-1-yl-methanone

Chemical Property of 1-Benzoylpyren

Chemical Property:

Purity/Quality:

98%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Benzoylpyren

There total 26 articles about 1-Benzoylpyren which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tert-butyl benzoyl(tert-butoxycarbonyl)carbamate (135364-97-5) + 1-pyrenylboronic acid (164461-18-1) → phenylpyren-1-yl-methanone (7376-03-6)

Guidance literature:

With potassium fluoride; (3-phenylallyl)(chloro)-[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II); In water; toluene; at 23 ℃; for 15h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.orglett.7b03191

Reference yield: 88.0%

benzoic acid phenyl ester (93-99-2) + 1-pyrenylboronic acid (164461-18-1) → phenylpyren-1-yl-methanone (7376-03-6)

Guidance literature:

With [(1,3-bis-(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene)PdCl(μ-Cl)]₂; potassium carbonate; In tetrahydrofuran; water; at 23 ℃; for 12h;

DOI:10.1039/d1cy00312g

Reference yield: 85.0%

phenyl(pyren-1-yl)methanol (95811-57-7) → phenylpyren-1-yl-methanone (7376-03-6)

Guidance literature:

With sodium nitrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; Zr₆O₄(OH)₄(2,2'-bipyridyl-5,5'-dicarboxylato-Eu)_4.5(2,2'-bipyridyl-5,5'-dicarboxylato)_1.5(NO₃)_13.5; acetic acid; In toluene; at 60 ℃; for 18h; Reagent/catalyst;

DOI:10.1039/d0dt01324b

upstream raw materials:

pyrene

benzoyl chloride

benzoic acid 2,3,5,6-tetrafluorophenyl ester

benzoic acid N-hydroxysuccinimide ester

Downstream raw materials:

phenyl(pyren-1-yl)methanol

1-Thiobenzoyl-pyren

hydroxy-diphenyl-(pyrenyl-⁽¹⁾)-methane

pyranthrone

Refernces

• 1、 Rawe, Benjamin W.,Brown, Christopher M.,Mackinnon, Marc R.,Patrick, Brian O.,Bodwell, Graham J.,Gates, Derek P.. "A C-Pyrenyl Poly(methylenephosphine): Oxidation "turns On" Blue Photoluminescence in Solution and the Solid State". . p. 2520 - 2526. Retrieved 2017.
• 2、 Cavallo, Luigi,Nolan, Steven P.,Poater, Albert,Szostak, Michal,Yang, Shiyi,Zhou, Tongliang. "Suzuki-Miyaura cross-coupling of esters by selective O-C(O) cleavage mediated by air- And moisture-stable [Pd(NHC)(μ-Cl)Cl]2precatalysts: Catalyst evaluation and mechanism". . p. 3189 - 3197. Retrieved 2021/05/25.
• 3、 Jeoung, Sungeun,Kim, Min,Kim, Seongwoo,Lee, Jooyeon,Moon, Hoi Ri. "Dual-fixations of europium cations and TEMPO species on metal-organic frameworks for the aerobic oxidation of alcohols". supporting information. p. 8060 - 8066. Retrieved 2020/07/10.