1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol

Base Information

• Chemical Name: 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol
• CAS No.: 154372-20-0
• Molecular Formula: C₃₈H₄₂O₇
• Molecular Weight: 610.747
• Mol file: 154372-20-0.mol

Synonyms:1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol

Chemical Property of 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol

There total 25 articles about 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

benzyl bromide (100-39-0) + (+)-6-O-allyl-1-O-(p-methoxybenzyl)-4,5-di-O-benzyl-myo-inositol (475650-91-0) → 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol (154372-20-0)

Guidance literature:

(+)-6-O-allyl-1-O-(p-methoxybenzyl)-4,5-di-O-benzyl-myo-inositol; With di(n-butyl)tin oxide; In toluene; for 2.5h; Heating;

benzyl bromide; In N,N-dimethyl-formamide; at 20 ℃; for 15h;

DOI:10.1016/S0960-894X(02)00301-3

Reference yield: 94.0%

p-methoxybenzyl chloride (824-94-2) + (-)-6-O-allyl-3,4,5-tri-O-benzyl-myo-inositol (154459-81-1,1214020-75-3) → 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol (154372-20-0)

Guidance literature:

(-)-6-O-allyl-3,4,5-tri-O-benzyl-myo-inositol; With di(n-butyl)tin oxide; In toluene; for 2.5h; Heating;

p-methoxybenzyl chloride; In N,N-dimethyl-formamide; at 20 ℃; for 16h;

DOI:10.1016/S0960-894X(02)00301-3

Reference yield: 72.0%

C38H40O7 (1185996-05-7) → 1D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzoyl)-myo-inositol (154372-20-0)

Guidance literature:

With hydrogenchloride; sodium cyanoborohydride; In tetrahydrofuran; diethyl ether; at 0 ℃; regiospecific reaction;

DOI:10.1016/j.bmcl.2009.03.151

upstream raw materials:

p-methoxybenzyl chloride

(-)-6-O-allyl-3,4,5-tri-O-benzyl-myo-inositol

benzyl bromide

(+)-6-O-allyl-1-O-(p-methoxybenzyl)-4,5-di-O-benzyl-myo-inositol

Downstream raw materials:

1D-6-O-Allyl-3,4,5-tri-O-benzyl-2-O-methyl-1-O-(4-methoxybenzyl)-myo-inositol

1-D-6-O-allyl-3,4,5-tri-O-benzyl-1-O-(4-methoxybenzyl)-2-O-octyl-myo-inositol

1-D-6-O-allyl-3,4,5-tri-O-benzyl-2-O-hexadecyl-1-O-(4-methoxybenzyl)-myo-inositol

(-)-6-O-allyl-2-O-hexadecanoyl-1-O-(p-methoxybenzyl)-3,4,5-tri-O-benzyl-myo-inositol