{2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

Base Information

Chemical Name:{2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane
CAS No.:201004-61-7
Molecular Formula:C₂₄H₃₉ClO₄Si
Molecular Weight:455.11
Hs Code.:

Synonyms:{2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

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Chemical Property of {2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

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Technology Process of {2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

There total 3 articles about {2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 201004-60-6
(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

: 201004-61-7
{2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

Guidance literature:: With 2,4,6-trimethyl-pyridine; methanesulfonyl chloride; lithium chloride; In N,N-dimethyl-formamide; at 0 ℃; for 1h;
DOI:10.1002/(SICI)1099-0690(199801)1998:1<43::AID-EJOC43>3.0.CO;2-L

Reference yield:

: 184762-94-5
[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-acetaldehyde

: 201004-61-7
{2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 81 percent / 18-crown-6-acetonitrile complex, potassium bis(trimethylsilyl)amide / tetrahydrofuran; toluene / 0.5 h / -78 °C

2: 85 percent / LiAlH₄ / diethyl ether / 1 h / 0 °C

3: 94 percent / lithium chloride, sym-collidine, methanesulfonyl chloride / dimethylformamide / 1 h / 0 °C

With 2,4,6-trimethyl-pyridine; lithium aluminium tetrahydride; potassium hexamethylsilazane; methanesulfonyl chloride; 18-crown-6 complexed with acetonitrile; lithium chloride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide; toluene;
DOI:10.1002/(SICI)1099-0690(199801)1998:1<43::AID-EJOC43>3.0.CO;2-L

Reference yield:

: 201004-59-3
(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-enoic acid ethyl ester

: 201004-61-7
{2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / LiAlH₄ / diethyl ether / 1 h / 0 °C

2: 94 percent / lithium chloride, sym-collidine, methanesulfonyl chloride / dimethylformamide / 1 h / 0 °C

With 2,4,6-trimethyl-pyridine; lithium aluminium tetrahydride; methanesulfonyl chloride; lithium chloride; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1002/(SICI)1099-0690(199801)1998:1<43::AID-EJOC43>3.0.CO;2-L