(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

Base Information

Chemical Name:(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol
CAS No.:201004-60-6
Molecular Formula:C₂₄H₄₀O₅Si
Molecular Weight:436.664
Hs Code.:

Synonyms:(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

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Chemical Property of (Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

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Technology Process of (Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

There total 2 articles about (Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 201004-59-3
(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-enoic acid ethyl ester

: 201004-60-6
(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 1h;
DOI:10.1002/(SICI)1099-0690(199801)1998:1<43::AID-EJOC43>3.0.CO;2-L

Reference yield:

: 184762-94-5
[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-acetaldehyde

: 201004-60-6
(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / 18-crown-6-acetonitrile complex, potassium bis(trimethylsilyl)amide / tetrahydrofuran; toluene / 0.5 h / -78 °C

2: 85 percent / LiAlH₄ / diethyl ether / 1 h / 0 °C

With lithium aluminium tetrahydride; potassium hexamethylsilazane; 18-crown-6 complexed with acetonitrile; In tetrahydrofuran; diethyl ether; toluene;
DOI:10.1002/(SICI)1099-0690(199801)1998:1<43::AID-EJOC43>3.0.CO;2-L

Reference yield: 94.0%

: 201004-60-6
(Z)-4-[3,4-Dimethyl-5-(tetrahydro-pyran-2-yloxy)-2-(2-trimethylsilanyl-ethoxymethoxy)-phenyl]-2-methyl-but-2-en-1-ol

: 201004-61-7
{2-[6-((Z)-4-Chloro-3-methyl-but-2-enyl)-2,3-dimethyl-4-(tetrahydro-pyran-2-yloxy)-phenoxymethoxy]-ethyl}-trimethyl-silane

Guidance literature:: With 2,4,6-trimethyl-pyridine; methanesulfonyl chloride; lithium chloride; In N,N-dimethyl-formamide; at 0 ℃; for 1h;
DOI:10.1002/(SICI)1099-0690(199801)1998:1<43::AID-EJOC43>3.0.CO;2-L