tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane

Base Information

• Chemical Name: tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane
• CAS No.: 304915-84-2
• Molecular Formula: C₁₅H₂₈O₂Si
• Molecular Weight: 268.472
• Mol file: 304915-84-2.mol

Synonyms:tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane

Chemical Property of tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane

There total 5 articles about tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1,5-dimethoxy-1,4-cyclohexadiene (37567-78-5) + dimethyl sulfate (77-78-1) → tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane (304915-84-2)

Guidance literature:

Multistep reaction;

DOI:10.1002/1521-3773(20000901)39:17<3080::AID-ANIE3080>3.0.CO;2-E

Reference yield: 78.0%

1,5-dimethoxy-1,4-cyclohexadiene (37567-78-5) + tert-butyldimethylsilyl chloride (18162-48-6) + dimethyl sulfate (77-78-1) → tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane (304915-84-2)

Guidance literature:

Multistep reaction;

DOI:10.1002/1522-2675(200210)85:10<3559::AID-HLCA3559>3.0.CO;2-6

Reference yield:

dimethyl sulfate (77-78-1) + (tert-butyl)(2,6-dimethoxycyclohexa-2,5-dienyl)dimethylsilane → tert-butyl(2,6-dimethoxy-1-methylcyclohexa-2,5-dien-1-yl)dimethylsilane (304915-84-2)

Guidance literature:

(tert-butyl)(2,6-dimethoxycyclohexa-2,5-dienyl)dimethylsilane; With n-butyllithium; In tetrahydrofuran; hexane; pentane; at -20 - -15 ℃; for 1.25h;

dimethyl sulfate; In tetrahydrofuran; hexane; pentane; at -20 - 20 ℃;

DOI:10.1021/ja0341743

upstream raw materials:

1,5-dimethoxy-1,4-cyclohexadiene

dimethyl sulfate

tert-butyldimethylsilyl chloride

Downstream raw materials:

tert-butyldimethyl(3-phenylpropoxy)silane

[4-(benzyloxy)butoxy](tert-butyl)dimethylsilane

1-(tert-butyldimethylsiloxy)cyclohexane