rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane

Base Information

Chemical Name:rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane
CAS No.:1353023-69-4
Molecular Formula:C₁₇H₃₁IOSi
Molecular Weight:406.423
Hs Code.:

Synonyms:rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane

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Technology Process of rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane

There total 1 articles about rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 817203-15-9
rac-(E)-3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-en-1-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1353023-69-4
rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 25 ℃; for 4.5h; Inert atmosphere;
DOI:10.1002/ejoc.201100935

Reference yield: 80.0%

: (2E,4E,6E)-3,7-dimethyl-9-(tri-n-butylstannyl)hepta-2,4,6-trienol

: 1353023-69-4
rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane

: 1353023-70-7
rac-all-trans-4-(tert-butyldimethylsilyloxy)retinol

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; Tetrabutylammoniumsalz der Diphenylphosphinsaeure; In N,N-dimethyl-formamide; at 25 ℃; for 2h; Inert atmosphere;
DOI:10.1002/ejoc.201100935

Reference yield:

: 1353023-69-4
rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane

: 1353023-74-1
rac-tert-butyl-{3-[(1E,3E,5E,7E)-3,7-dimethyldeca-1,3,5,7,9-pentaenyl]-2,4,4-trimethylcyclohex-2-enyloxy}dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; Tetrabutylammoniumsalz der Diphenylphosphinsaeure / N,N-dimethyl-formamide / 2 h / 25 °C / Inert atmosphere

2.1: pyridine; Dess-Martin periodane / dichloromethane / 4 h / 0 °C / Inert atmosphere

3.1: sodium hexamethyldisilazane / tetrahydrofuran; hexane / 0.5 h / 25 °C / Inert atmosphere

3.2: 1 h / -78 °C / Inert atmosphere

With pyridine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; sodium hexamethyldisilazane; Dess-Martin periodane; Tetrabutylammoniumsalz der Diphenylphosphinsaeure; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; 1.1: Stille coupling / 3.1: Wittig reaction / 3.2: Wittig reaction;
DOI:10.1002/ejoc.201100935