CuCl(bipyridine)

Base Information

• Chemical Name: CuCl(bipyridine)
• CAS No.: 39583-95-4
• Molecular Formula: C₁₀H₈ClCuN₂
• Molecular Weight: 255.186

Synonyms:CuCl(bipyridine)

Chemical Property of CuCl(bipyridine)

Chemical Property:

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Technology Process of CuCl(bipyridine)

There total 3 articles about CuCl(bipyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

CuCl2(C4H9NH2)2 (52518-95-3) + bis(carbomethoxy)palladium bipyridine → dichloro(2,2'-bipyridine)palladium(II) (14871-92-2) + CuCl(bipyridine) (39583-95-4) + methyl N-butylcarbamate (2594-21-0) + n-butylamine hydrochloride (3858-78-4) + N-butylamine (109-73-9,85404-21-3)

Guidance literature:

With nitrogen; In tetrahydrofuran; byproducts: CuCl; Pd-compd. in THF and CuCl2(BuNH2)2 in a Cu/Pd molar ratio of 4:1 are loaded sep. in the 2 branches of an inverted-Y glass reactor. Reactor is closed under N2, contents are mixed and stirred for 1 h.; IR, GC-MS and GLC anal. of liq. phase shows presence of BuNH2COOCH3. Filtn. of solid residue (anaerobic conditions), sepn. of PdCl2(bipy) from CuCl by addn. of MeOH soln. contg. bipy, IR, elem. anal. Removal of MeOH(vac.) gives CuCl(bipy). Elem. anal.;

DOI:10.1016/0022-328X(94)80174-6

Reference yield:

Pd(COOCH3)2(P(C6H5)3)2 + copper dichloride → PdCl(CO2CH3)(P(C6H5)3)2 + CuCl(bipyridine) (39583-95-4) + methyl chloroformate (79-22-1)

Guidance literature:

With [2,2]bipyridinyl; In tetrahydrofuran; the suspn. of the Pd-compd. and CuCl2 in THF is stirred for 1h in a closed glas reactor under N2, filtn. (in the liquid phase is CH3OCOCl, detected by IR), addn. of bipy in MeOH to the residue; filtn. (in the liquid phase is the Cu-compd., evapd. (vac.), elem. anal.), elem. anal.;

DOI:10.1016/0022-328X(93)83031-P

Reference yield:

bis(carbomethoxy)palladium bipyridine + copper dichloride → dichloro(2,2'-bipyridine)palladium(II) (14871-92-2) + CuCl(bipyridine) (39583-95-4) + methyl chloroformate (79-22-1)

Guidance literature:

With [2,2]bipyridinyl; In tetrahydrofuran; the suspn. of the Pd-compd. in THF is stirred with CuCl2 in THF in a closed glass reactor under N2 for 1 h, filtn. (in the liquid phase is CH3OCOCl, detected by IR), addn. of bipy in MeOH to the residue; filtn. (the residue is the Pd-compd., elem. anal.), soln. is evapd. in vac., elem. anal.;

DOI:10.1016/0022-328X(93)83031-P

upstream raw materials:

CuCl₂(C₄H₉NH₂)2

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