(5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane

Base Information

Chemical Name:(5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane
CAS No.:1437789-15-5
Molecular Formula:C₂₆H₄₄O₄Si
Molecular Weight:448.718
Hs Code.:

Synonyms:(5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane

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Chemical Property of (5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane

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Technology Process of (5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane

There total 12 articles about (5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 4938-52-7,67928-91-0,87247-56-1,87247-44-7
(S)-Hept-1-en-3-ol

: 7751-38-4
Diisopropylsilyl dichloride

: 338956-97-1
(3R)-5-[(4-methoxybenzyl)oxy]pent-1-en-3-ol

: 1437789-15-5
(5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane

Guidance literature:: (S)-Hept-1-en-3-ol; Diisopropylsilyl dichloride; With 1H-imidazole; In dichloromethane; at 0 ℃; for 1.25h; Inert atmosphere;

(3R)-5-[(4-methoxybenzyl)oxy]pent-1-en-3-ol; In dichloromethane; at 20 ℃; for 14h; Inert atmosphere;
DOI:10.1002/ejoc.201300302

Reference yield:

: 195257-62-6
(R)-2-(2-((4-methoxybenzyl)oxy)ethyl)oxirane

: 1437789-15-5
(5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -20 °C / Inert atmosphere

1.2: 2 h / -20 - 25 °C / Inert atmosphere

2.1: 1H-imidazole / dichloromethane / 1.17 h / 0 °C / Inert atmosphere

2.2: 4 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1016/j.tetasy.2013.04.004

Reference yield:

: 1436-34-6,104898-06-8,122922-40-1,130404-08-9
(S)-1,2-epoxyhexane

: 1437789-15-5
(5R,9S)-7,7-diisopropyl-1-(4-methoxyphenyl)-5,9-divinyl-2,6,8-trioxa-7-silatridecane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -20 °C / Inert atmosphere

1.2: 2 h / -20 - 25 °C / Inert atmosphere

2.1: 1H-imidazole / dichloromethane / 1.17 h / 0 °C / Inert atmosphere

2.2: 4 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; n-butyllithium; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1016/j.tetasy.2013.04.004