methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate

Base Information

Chemical Name:methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate
CAS No.:166392-57-0
Molecular Formula:C₂₀H₃₂O₆
Molecular Weight:368.47
Hs Code.:

Synonyms:methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate

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Chemical Property of methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate

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Technology Process of methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate

There total 3 articles about methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 67-56-1
methanol

: (3S,8S,11S)-11-(4-methoxycarbonylbutyl)-2,9-dioxatricyclo<9.4.0.0^3,8>pentadec-1(15)en-10-one

: 166392-57-0
methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate

Guidance literature:: With sodium; for 1h; Ambient temperature;

Reference yield:

: 5454-83-1
5-bromovaleric acid methyl ester

: 166392-57-0
methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 48 percent / BuLi, diisopropylamine, HMPA / hexane; tetrahydrofuran / 1.) -78 deg C, 10 min, 2.) -78 deg C, 1 h; -40 deg C, 24 h

2: 84 percent / Na / 1 h / Ambient temperature

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; sodium; diisopropylamine; In tetrahydrofuran; hexane;

Reference yield:

: 142977-18-2
(3S,8S)-2,9-dioxa-10-oxotricyclo<9,4,0,0^3,8>pentadec-1(11)-ene

: 166392-57-0
methyl (1S)-2-<(1S,2S)-2-hydroxycyclohexyloxy>-1-(4-methoxycarbonylbut)cyclohex-2-enecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 48 percent / BuLi, diisopropylamine, HMPA / hexane; tetrahydrofuran / 1.) -78 deg C, 10 min, 2.) -78 deg C, 1 h; -40 deg C, 24 h

2: 84 percent / Na / 1 h / Ambient temperature

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; sodium; diisopropylamine; In tetrahydrofuran; hexane;