1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal)

Base Information

• Chemical Name: 1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal)
• CAS No.: 102437-83-2
• Molecular Formula: C₃₂H₅₂N₆O₈
• Molecular Weight: 648.8
• Mol file: 102437-83-2.mol

Synonyms:1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal)

Chemical Property of 1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal)

There total 2 articles about 1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

1,1,4,4-tetraethoxy-2-butyne (3975-08-4) + 1,3-bis(azidomethyl)benzene (102437-80-9) → 1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal) (102437-83-2)

Guidance literature:

In ethanol; at 90 ℃; for 30h;

DOI:10.1021/je00045a038

Reference yield:

3-(chloromethyl)benzyl chloride (626-16-4) → 1,1'-<1,3-phenylenebis(methylene)>bis(triazole-4,5-dicarboxyaldehyde) tetrakis(ethyl acetal) (102437-83-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 88 percent / sodium azide / H₂O; methanol / 48 h / 100 °C

2: 78 percent / ethanol / 30 h / 90 °C

With sodium azide; In methanol; ethanol; water;

DOI:10.1021/je00045a038

upstream raw materials:

1,1,4,4-tetraethoxy-2-butyne

1,3-bis(azidomethyl)benzene

3-(chloromethyl)benzyl chloride