7-Oxabicyclo[2.2.1]hept-2-ene

Base Information

• Chemical Name: 7-Oxabicyclo[2.2.1]hept-2-ene
• CAS No.: 6705-50-6
• Molecular Formula: C6H8 O
• Molecular Weight: 96.1289
• Hs Code.: 2932999099
• Mol file: 6705-50-6.mol

Synonyms:7-Oxabicyclo[2.2.1]hept-5-ene;7-Oxanorbornene; Cyclohexene, 3,6-epoxy-

Chemical Property of 7-Oxabicyclo[2.2.1]hept-2-ene

Chemical Property:

• Vapor Pressure: 13.3mmHg at 25°C
• Boiling Point: 127.8°C at 760 mmHg
• Flash Point: 19.2°C
• PSA: 9.23000
• Density: 1.073g/cm³
• LogP: 1.10380

Purity/Quality:

99% ^*data from raw suppliers

7-Oxanorbornene(90%Purity) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 7-Oxanorbornene can be used as reactant/reagent in preparation of cyclometalated arylpyridine, arylquinoline and arylphenanthridine iridium and platinum complexes as phosphorescent emitters for organic electroluminescent devices.

Technology Process of 7-Oxabicyclo[2.2.1]hept-2-ene

There total 12 articles about 7-Oxabicyclo[2.2.1]hept-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

2-exo-methoxy-3-endo-(phenylsulfonyl)-7-oxabicyclo<2.2.1>heptane → 7-oxa-bicyclo[2.2.1]hept-2Z-ene (6705-50-6) + 2-exo-methoxy-7-oxabicyclo<2.2.1>heptane

Guidance literature:

With sodium dihydrogenphosphate; sodium amalgam; In N,N-dimethyl-formamide; Ambient temperature;

DOI:10.1021/jo00222a028

Reference yield:

exo-7-oxabicyclo<2.2.1>hept-2-phenylsulphonyl-5-ene → 7-oxa-bicyclo[2.2.1]hept-2Z-ene (6705-50-6) + 4-(hydroxymethyl)cyclopentene (25125-21-7) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

With sodium dihydrogenphosphate; sodium amalgam; In methanol; at 0 ℃;

DOI:10.1021/jo00222a028

Reference yield:

furan (110-00-9) + ethene (74-85-1) → 7-oxa-bicyclo[2.2.1]hept-2Z-ene (6705-50-6)

Guidance literature:

With hydroquinone; at 155 ℃; under 55163.1 Torr;

DOI:10.1021/ja01230a508

upstream raw materials:

furan

ethene

(+/-)-trans-2,3-bis(phenylsulfonyl)-7-oxabicyclo[2.2.1]hept-5-ene

2-(phenylsulfonyl)-7-oxabicyclo<2.2.1>hept-2-ene

Downstream raw materials:

furan

ethene

{3-[(1R,2S,3S,4S)-3-((S)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid

{3-[(1R,2S,3S,4S)-3-((S)-3-Hydroxy-oct-1-ynyl)-7-oxa-bicyclo[2.2.1]hept-2-ylmethyl]-phenoxy}-acetic acid methyl ester