Technology Process of C28H37Cl3O8Si
There total 1 articles about C28H37Cl3O8Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve;
In
dichloromethane;
at -30 ℃;
for 3.5h;
DOI:10.1055/s-2007-970766
- Guidance literature:
-
Multi-step reaction with 8 steps
1: 86 percent / N-iodosuccinimide; trifluoromethanesulfonic acid; 4 Angsroem molecular sieves / CH2Cl2 / 3.5 h / -30 °C
2: 85 percent / Zn; Ac2O; AcOH / tetrahydrofuran / 2.5 h / 20 °C
3: Dess-Martin periodinane; NaHCO3 / CH2Cl2 / 3 h / 20 °C
4: NaClO2 / 2-methyl-propan-2-ol; aq. phosphate buffer; various solvent(s) / 12 h / 20 °C
5: 1-[3-(dimethylamino)propyl]-3-ethylcarbodiimide*HCl; pyridine / CH2Cl2 / 4 h / 20 °C
6: trifluoroacetic acid / CH2Cl2 / 2 h / 20 °C
7: 79 percent / DBU / CH2Cl2 / 2 h / 0 °C
8: 77 percent / CH2Cl2 / 24 h / 20 °C
With
pyridine; sodium chlorite; N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; acetic anhydride; sodium hydrogencarbonate; Dess-Martin periodane; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; trifluoroacetic acid; zinc;
In
tetrahydrofuran; phosphate buffer; dichloromethane; tert-butyl alcohol;
3: Dess-Martin oxidation;
DOI:10.1055/s-2007-970766
