7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene

Base Information

• Chemical Name: 7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene
• CAS No.: 171001-64-2
• Molecular Formula: C₄₈H₃₈O₄Sb₂
• Molecular Weight: 922.327
• Mol file: 171001-64-2.mol

Synonyms:7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene

Chemical Property of 7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene

There total 1 articles about 7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

triphenylantimony (603-36-1) + recorcinol (108-46-3) → 7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene (171001-64-2)

Guidance literature:

With tert.-butylhydroperoxide; In benzene; byproducts: tert-butanol, water; hydroperoxide soln. slow addn. to soln. of Sb-compd. and diphenol (ice bath); volatile product removing by cold trap, solid residue re-crystn. (benzene-hexane); elem. anal., cryoscopy;

DOI:10.1007/BF00698512

Reference yield: 85.0%

hydrogenchloride (7647-01-0,15364-23-5) + 7,7,7,15,15,15-hexaphenyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene (171001-64-2) → triphenylantimony dichloride (594-31-0,34716-91-1,20265-29-6) + benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9)

Guidance literature:

In ethanol; excess soln. of acid addn. to Sb-compd., heating (3 h, reflux, water bath), soln. pouring to petri dish; sepn. by different solubility in benzene;

DOI:10.1007/BF00698512

upstream raw materials:

triphenylantimony

recorcinol

Downstream raw materials:

triphenylantimony dichloride

benzene-1,2-diol