trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III)

Base Information

• Chemical Name: trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III)
• CAS No.: 1286784-29-9
• Molecular Formula: C₂₂H₁₇Cl₃IrN₃O
• Molecular Weight: 637.975
• Mol file: 1286784-29-9.mol

Synonyms:trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III)

Chemical Property of trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III)

There total 4 articles about trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

4′-(4-hydroxymethylphenyl)-2,2′:6′,2′′-terpyridine (447399-94-2) + iridium(III) chloride n-hydrate → trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III) (1286784-29-9)

Guidance literature:

In ethylene glycol; at 160 ℃; for 0.25h; Darkness; Inert atmosphere;

DOI:10.3390/molecules18088959

Reference yield: 47.0%

4′-(4-hydroxymethylphenyl)-2,2′:6′,2′′-terpyridine (447399-94-2) + iridium(III) chloride hydrate → trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III) (1286784-29-9)

Guidance literature:

In ethylene glycol; (N2) IrCl3 and ligand (1:1) in ethylene glycol were heated at 160°C in the dark for 15 min; ppt. was filtered, washed with H2O, EtOH and Et2O;

DOI:10.1039/c0dt01317j

Reference yield:

2-acetylpyridine (1122-62-9) → trichloro(4′-(4-hydroxymethylphenyl)-2,2′:6′2′′-terpyridine)iridium(III) (1286784-29-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium hydroxide / 0.08 h / 0 °C

1.2: 2 h / 0 °C

2.1: ethylene glycol / 0.25 h / 160 °C / Darkness; Inert atmosphere

With sodium hydroxide; In ethylene glycol;

DOI:10.3390/molecules18088959

upstream raw materials:

4′-(4-hydroxymethylphenyl)-2,2′:6′,2′′-terpyridine

2-acetylpyridine

4-(hydroxylmethyl)benzaldehyde