(1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene^(1-))GeCl

Base Information

• Chemical Name: (1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene^(1-))GeCl
• CAS No.: 812645-94-6
• Molecular Formula: C₃₆H₄₀ClGeN₂
• Molecular Weight: 608.77
• Mol file: 812645-94-6.mol

Synonyms:(1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene^(1-))GeCl

Chemical Property of (1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene^(1-))GeCl

Chemical Property:

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Technology Process of (1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene^(1-))GeCl

There total 2 articles about (1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene^(1-))GeCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

germanium(II) chloride dioxane + 1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene (153625-67-3) → (1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene(1-))GeCl (812645-94-6)

Guidance literature:

With Na; In diethyl ether; byproducts: NaCl; under vac. using Schlenk ampules; ligand and Na stirred for 24 h in Et2O, Ge complex added; centrifuged, decanted, isolated from the concd. Et2O soln.;

DOI:10.1021/ic048801g

Reference yield: 21.0%

germanium(II) chloride dioxane + 1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene (153625-67-3) → hexachlorodigermane (15432-44-7) + (1,2-bis((2,6-diisopropylphenyl)imino)acenaphthene(1-))GeCl (812645-94-6)

Guidance literature:

In diethyl ether; under vac. using Schlenk ampules; Ge complex added to a suspn. of ligand, shaken at room temp.; filtered, concd. (vac.), crystd. for 2 d; elem. anal.;

DOI:10.1021/ic048801g

upstream raw materials:

1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene