2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine

Base Information

Chemical Name:2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine
CAS No.:221910-92-5
Molecular Formula:C₃₁H₂₈N₄O₄S₄
Molecular Weight:648.852
Hs Code.:

2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6<i>H</i>,12<i>H</i>-5,11-methano-dibenzo[<i>b</i>,<i>f</i>][1,5]diazocine

Synonyms:2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine

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Chemical Property of 2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine

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Technology Process of 2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine

There total 3 articles about 2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 221910-91-4
4-(4-nitro-benzyldisulfanylmethyl)-phenylamine

: 221910-92-5
2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; ethanol; at 50 ℃; for 24h;
DOI:10.1016/S0040-4039(98)02609-4

Reference yield:

: 39549-05-8
bis(4-nitrobenzyl)disulfide

: 221910-92-5
2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / SnCl₂*2H₂O / ethyl acetate / 0.83 h / 70 °C

2: 35 percent / aq. HCl / tetrahydrofuran; ethanol / 24 h / 50 °C

With hydrogenchloride; tin(ll) chloride; In tetrahydrofuran; ethanol; ethyl acetate;
DOI:10.1016/S0040-4039(98)02609-4

Reference yield:

: 100-14-1
4-nitrobenzyl chloride

: 221910-92-5
2,8-bis-(4-nitro-benzyldisulfanylmethyl)-6H,12H-5,11-methano-dibenzo[b,f][1,5]diazocine

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Na₂S₂O₃*5H₂O; 2.) aq. H₂SO₄; 3.) I₂ / 3.) ethanol

2: 52 percent / SnCl₂*2H₂O / ethyl acetate / 0.83 h / 70 °C

3: 35 percent / aq. HCl / tetrahydrofuran; ethanol / 24 h / 50 °C

With hydrogenchloride; sulfuric acid; iodine; sodium thiosulfate; tin(ll) chloride; In tetrahydrofuran; ethanol; ethyl acetate;
DOI:10.1016/S0040-4039(98)02609-4