methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate

Base Information

Chemical Name:methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate
CAS No.:1326662-82-1
Molecular Formula:C₂₇H₃₀O₇
Molecular Weight:466.531
Hs Code.:

Synonyms:methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate

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Chemical Property of methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate

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Technology Process of methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate

There total 1 articles about methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)styryl]biphenyl-2-carboxylate

: 1326662-82-1
methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate

Guidance literature:: With 20 % Pd(OH)2/C; hydrogen; In N,N-dimethyl-formamide; at 20 ℃; for 20h;
DOI:10.1016/j.tet.2011.06.018

Reference yield: 100.0%

: 1326662-82-1
methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate

: 1326662-84-3
2-hydroxymethyl-2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl

Guidance literature:: methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate; With diisobutylaluminium hydride; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 2h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; hexane; water; at 0 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2011.06.018

Reference yield:

: 1326662-82-1
methyl 2',4-dimethoxy-4'-[4-methoxy-3-(methoxymethoxy)phenethyl]biphenyl-2-carboxylate

: 1326662-64-9
(Z)-2-(4-fluoro-3-nitrostyryl)-2',4-dimethoxy-4'-(3-hydroxy-4-methoxyphenethyl)biphenyl

Guidance literature:: Multi-step reaction with 4 steps

1.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / 2 h / -78 - 20 °C / Inert atmosphere

1.2: 0 °C / Inert atmosphere

2.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 2 h / 0 - 20 °C

3.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / 0 - 20 °C / Inert atmosphere

3.2: 24 h / 0 - 20 °C / Inert atmosphere

4.1: hydrogenchloride; water / 1,4-dioxane / 3 h / 70 °C

With hydrogenchloride; water; sulfur trioxide pyridine complex; potassium hexamethylsilazane; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; 1,4-dioxane; hexane; dichloromethane; dimethyl sulfoxide; toluene; 3.2: Wittig reaction;
DOI:10.1016/j.tet.2011.06.018