3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

Base Information

Chemical Name:3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol
CAS No.:1357098-64-6
Molecular Formula:C₂₈H₂₉FO₄
Molecular Weight:448.534
Hs Code.:

Synonyms:3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

Suppliers and Price of 3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

There total 9 articles about 3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 1271-66-5
dimethyltitanocene

: 1357098-63-5
2,3,4-tri-O-benzyl-6-deoxy-6-fluoro-D-mannono-1,5-lactone

: 1357098-64-6
3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

Guidance literature:: In toluene; at 60 ℃; for 24h; Inert atmosphere; Darkness;

Reference yield:

: 953817-79-3
phenyl 2,3,4-tri-O-benzyl-6-deoxy-6-fluoro-1-thio-α-D-mannopyranoside

: 1357098-64-6
3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

Guidance literature:: Multi-step reaction with 3 steps

1: N-Bromosuccinimide; water / acetone / 0.5 h / 20 °C

2: acetic anhydride / dimethyl sulfoxide / 24 h / 30 °C

3: toluene / 24 h / 60 °C / Inert atmosphere; Darkness

With N-Bromosuccinimide; water; acetic anhydride; In dimethyl sulfoxide; acetone; toluene;

Reference yield:

: phenyl 6-deoxy-6-fluoro-1-thio-α-D-mannopyranoside

: 1357098-64-6
3,4,5-tri-O-benzyl-2,6-anhydro-1,7-dideoxy-7-fluoro-D-mannohept-1-enitol

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 2 h / 0 - 20 °C / Inert atmosphere

1.2: 20 °C / Inert atmosphere

2.1: N-Bromosuccinimide; water / acetone / 0.5 h / 20 °C

3.1: acetic anhydride; dimethyl sulfoxide / 12 h / 30 °C

4.1: toluene / 24 h / 60 °C / Inert atmosphere; Darkness

With N-Bromosuccinimide; water; acetic anhydride; sodium hydride; dimethyl sulfoxide; In N,N-dimethyl-formamide; acetone; toluene; mineral oil;
DOI:10.1002/ejoc.201101238