Technology Process of 1-bromo-4-(1-methylcycloprop-2-en-1-yl)benzene
There total 6 articles about 1-bromo-4-(1-methylcycloprop-2-en-1-yl)benzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium tert-butylate;
In
dimethyl sulfoxide;
at 20 ℃;
DOI:10.1021/jacs.7b06523
- Guidance literature:
-
Multi-step reaction with 3 steps
1: Bromoform; cetyltrimethylammonim bromide; sodium hydroxide / water / 30 h / Inert atmosphere; Schlenk technique
2: ethylmagnesium bromide; titanium(IV) isopropylate / diethyl ether / 4 h / 0 - 20 °C / Inert atmosphere; Schlenk technique
3: potassium tert-butylate / dimethyl sulfoxide / 20 °C / Inert atmosphere; Schlenk technique
With
titanium(IV) isopropylate; Bromoform; ethylmagnesium bromide; potassium tert-butylate; cetyltrimethylammonim bromide; sodium hydroxide;
In
diethyl ether; water; dimethyl sulfoxide;
DOI:10.1039/c7cc01368j
- Guidance literature:
-
Multi-step reaction with 4 steps
1: potassium tert-butylate; Methyltriphenylphosphonium bromide / diethyl ether / Inert atmosphere; Schlenk technique
2: Bromoform; cetyltrimethylammonim bromide; sodium hydroxide / water / 30 h / Inert atmosphere; Schlenk technique
3: ethylmagnesium bromide; titanium(IV) isopropylate / diethyl ether / 4 h / 0 - 20 °C / Inert atmosphere; Schlenk technique
4: potassium tert-butylate / dimethyl sulfoxide / 20 °C / Inert atmosphere; Schlenk technique
With
titanium(IV) isopropylate; Bromoform; ethylmagnesium bromide; potassium tert-butylate; cetyltrimethylammonim bromide; Methyltriphenylphosphonium bromide; sodium hydroxide;
In
diethyl ether; water; dimethyl sulfoxide;
DOI:10.1039/c7cc01368j