(R)-10-(t-butyldiphenylsilanyloxy)dodecanal

Base Information

Chemical Name:(R)-10-(t-butyldiphenylsilanyloxy)dodecanal
CAS No.:612070-04-9
Molecular Formula:C₂₈H₄₂O₂Si
Molecular Weight:438.726
Hs Code.:

Synonyms:(R)-10-(t-butyldiphenylsilanyloxy)dodecanal

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Chemical Property of (R)-10-(t-butyldiphenylsilanyloxy)dodecanal

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Technology Process of (R)-10-(t-butyldiphenylsilanyloxy)dodecanal

There total 8 articles about (R)-10-(t-butyldiphenylsilanyloxy)dodecanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 612070-03-8
(R)-10-(t-butyldiphenylsilanyloxy)dodecan-1-ol

: 612070-04-9
(R)-10-(t-butyldiphenylsilanyloxy)dodecanal

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; triethylamine; In dichloromethane; at -78 - 20 ℃;
DOI:10.1021/ol035254e

Reference yield:

: 112-43-6
10-Undecen-1-ol

: 612070-04-9
(R)-10-(t-butyldiphenylsilanyloxy)dodecanal

Guidance literature:: Multi-step reaction with 7 steps

1: 94 percent / NaH; tetra-t-butylammonium iodide / tetrahydrofuran / 0 °C

2: 95 percent / m-CPBA / CH₂Cl₂ / 12 h / 20 °C

3: acetic acid; air / (S,S)(Salen)CoIII(OAc) / toluene; H₂O / 35 h / 0 - 20 °C

4: 84 percent / CuLi₂Cl₄ / diethyl ether / 0.5 h / -10 °C

5: imidazole / acetonitrile / 12 h / 20 °C

6: 0.190 g / H₂ / Pd/C / hexane / 0.5 h

7: 75 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

With 1H-imidazole; oxalyl dichloride; dilithium tetrachlorocuprate; air; hydrogen; tetra(tert-butyl)ammonium iodide; sodium hydride; acetic acid; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; toluene; acetonitrile; 7: Swern oxidation;
DOI:10.1021/ol035254e

Reference yield:

: 81518-75-4
((undec-10-en-1-yloxy)methyl)benzene

: 612070-04-9
(R)-10-(t-butyldiphenylsilanyloxy)dodecanal

Guidance literature:: Multi-step reaction with 6 steps

1: 95 percent / m-CPBA / CH₂Cl₂ / 12 h / 20 °C

2: acetic acid; air / (S,S)(Salen)CoIII(OAc) / toluene; H₂O / 35 h / 0 - 20 °C

3: 84 percent / CuLi₂Cl₄ / diethyl ether / 0.5 h / -10 °C

4: imidazole / acetonitrile / 12 h / 20 °C

5: 0.190 g / H₂ / Pd/C / hexane / 0.5 h

6: 75 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

With 1H-imidazole; oxalyl dichloride; dilithium tetrachlorocuprate; air; hydrogen; acetic acid; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; In diethyl ether; hexane; dichloromethane; water; toluene; acetonitrile; 6: Swern oxidation;
DOI:10.1021/ol035254e