allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Base Information

Chemical Name:allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside
CAS No.:862476-87-7
Molecular Formula:C₂₂H₃₄O₆Si
Molecular Weight:422.594
Hs Code.:

Synonyms:allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Suppliers and Price of allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

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Technology Process of allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

There total 5 articles about allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 81600-93-3
allyl 4,6-di-O-benzylidene-α-D-mannopyranoside

: 862476-87-7
allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Guidance literature:: With triethylamine; In dichloromethane; N,N-dimethyl-formamide; at -20 ℃; for 1.5h;
DOI:10.1021/ol051038p

Reference yield: 33.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 81600-93-3
allyl 4,6-di-O-benzylidene-α-D-mannopyranoside

: 862476-87-7
allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Guidance literature:: With 1H-imidazole; dmap; In N,N-dimethyl-formamide; at 20 ℃; for 4h;
DOI:10.1021/ja3001584

Reference yield:

: 3458-28-4
D-Mannose

: 862476-87-7
allyl 4,6-O-benzylidene-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: BF₃*OEt₂

2: p-TsOH / dimethylformamide

3: 69 percent / Et₃N / CH₂Cl₂; dimethylformamide / 1.5 h / -20 °C

With boron trifluoride diethyl etherate; toluene-4-sulfonic acid; triethylamine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol051038p