methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

Base Information

Chemical Name:methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate
CAS No.:496916-51-9
Molecular Formula:C₁₉H₂₀FNO₁₂
Molecular Weight:473.366
Hs Code.:

Synonyms:methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

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Chemical Property of methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

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Technology Process of methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

There total 1 articles about methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 403-19-0
2-fluoro-4-nitrophenol

: 21085-72-3
1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester

: 496916-51-9
methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

Guidance literature:: With silver(l) oxide; In acetonitrile; at 20 ℃;
DOI:10.1039/b111549a

Reference yield: 85.0%

: 496916-51-9
methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

: 496916-52-0
methyl (2-fluoro-4-aminophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

Guidance literature:: With hydrogen; 10percent Pd/C; In ethanol; at 20 ℃;
DOI:10.1039/b111549a

Reference yield:

: 496916-51-9
methyl (2-fluoro-4-nitrophenyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronate

: 2-fluoro-4-[bis(2'-chloroethyl)amino]phenol

Guidance literature:: Multi-step reaction with 7 steps

1: 85 percent / H₂ / 10percent Pd/C / ethanol / 20 °C

2: 61 percent / acetic acid / 48 h / 20 °C

3: pyridine / 0.25 h / Heating

4: 164 mg / LiCl; pyridine / 1 h / Heating

5: 86 percent / NaOMe / CH₂Cl₂; methanol / -15 °C

6: 95 percent / aq. NaOH / acetone / 0.08 h / -15 °C

7: E. coli β-glucuronidase / aq. phosphate buffer / 37 °C / pH 7.2

With pyridine; sodium hydroxide; E. coli β-glucuronidase; hydrogen; sodium methylate; lithium chloride; 10percent Pd/C; In methanol; phosphate buffer; ethanol; dichloromethane; acetic acid; acetone;
DOI:10.1039/b111549a