(germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)

Base Information

Chemical Name:(germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)
CAS No.:912672-40-3
Molecular Formula:C₅₂H₅₃GePRuS₂
Molecular Weight:946.759
Hs Code.:

Synonyms:(germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)

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Chemical Property of (germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)

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Technology Process of (germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)

There total 3 articles about (germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 52490-94-5
[dichloro(p-cymene)(triphenylphosphane)ruthenium(II)]

: 384861-87-4
(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(SH)2

: 912672-40-3
(germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)

Guidance literature:: With BuLi; In tetrahydrofuran; toluene; (N2); std. Schlenk technique; soln. of BuLi in hexane was added to soln.of Ge complex in THF at -78°C; stirred for 30 min; Ru complex wa s added at -70°C; heated in toluene at 100°C;
DOI:10.1021/om060449m

Reference yield: 87.0%

: 912672-30-1
[(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-p-cymene)]

: 603-35-0
triphenylphosphine

: 912672-40-3
(germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)

Guidance literature:: In toluene; (N2); std. Schlenk technique; soln. of Ge-Ru complex and PPh3 in toluenewas stirred at 100°C for 16 h; volatiles removed (vac.); crystd. (toluene/hexane); elem. anal.;
DOI:10.1021/om060449m

Reference yield: 82.0%

: 912672-31-2
[(2,6-dimesitylphenyl)(2,6-diethylphenyl)Ge(μ-S)2Ru(η6-benzene)]

: 603-35-0
triphenylphosphine

: 912672-40-3
(germanium)(2,6-diethylphenyl)(2,6-dimesitylphenyl)bis-(μ-S)(ruthenium)(PPh3)

Guidance literature:: In toluene; (N2); std. Schlenk technique; soln. of Ge-Ru complex and PPh3 in toluenewas stirred at 100°C for 5 h; volatiles removed (vac.); crystd. (toluene/hexane);
DOI:10.1021/om060449m