Dichloro(p-cyMene)triphenylphosphinerutheniuM(II) dichloroMethane adduct, Min. 98%

Base Information

• Chemical Name: Dichloro(p-cyMene)triphenylphosphinerutheniuM(II) dichloroMethane adduct, Min. 98%
• CAS No.: 52490-94-5
• Molecular Formula: C₂₈H₂₉Cl₂PRu
• Molecular Weight: 568.488
• Mol file: 52490-94-5.mol

Synonyms:[dichloro(p-cymene)(triphenylphosphane)ruthenium(II)]

Chemical Property of Dichloro(p-cyMene)triphenylphosphinerutheniuM(II) dichloroMethane adduct, Min. 98%

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Dichloro(p-cymene)triphenylphosphineruthenium(II) dichloromethane adduct, min. 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dichloro(p-cyMene)triphenylphosphinerutheniuM(II) dichloroMethane adduct, Min. 98%

There total 9 articles about Dichloro(p-cyMene)triphenylphosphinerutheniuM(II) dichloroMethane adduct, Min. 98% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(p-cymene)ruthenium(II) chloride (100928-22-1) + triphenylphosphine (603-35-0) → [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)] (52490-94-5)

Guidance literature:

In dichloromethane; at 20 ℃; for 24h; Schlenk technique; Glovebox; Inert atmosphere;

DOI:10.1039/c7cc00787f

Reference yield: 70.0%

RuCl2(η(6)-p-cymene)(4-cyanopyridine) (154986-82-0) + triphenylphosphine (603-35-0) → [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)] (52490-94-5)

Guidance literature:

In methanol; N2-atmosphere; refluxing Ru-complex with 1 equiv. of PPh3; crystn. on cooling to room temp., filtration, washing (MeOH, Et2O), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(98)00571-3

Reference yield: 60.0%

dichloromethane (75-09-2) + C29H36Cl3N3Ru2*0.5CH2Cl2 + triphenylphosphine (603-35-0) → [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)] (52490-94-5) + C19H22ClN3Ru*CH2Cl2

Guidance literature:

In chloroform; at 20 ℃; for 1h; Schlenk technique;

DOI:10.1039/c4dt00551a

upstream raw materials:

RuCl2(η(6)-p-cymene)(4-cyanopyridine)

triphenylphosphine

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3)

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

Downstream raw materials:

[Ru(η6-C10H14)(PPh3)Cl(CNC5H4N)]PF6

[(η6-p-cymene)RuCl(PPh3)(imidazole)]BF4

(CH₃C₆H₄CH(CH₃)2)Ru(Br)(C₆H₅)(P(C₆H₅)3)

[Ru(η2-O2CO)(η6-p-cymene)(P(C6H5)3)]