1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene

Base Information

• Chemical Name: 1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene
• CAS No.: 1609257-11-5
• Molecular Formula: C₅₂H₅₃BrSi₂
• Molecular Weight: 814.068
• Mol file: 1609257-11-5.mol

Synonyms:1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene

Chemical Property of 1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene

There total 3 articles about 1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

4-bromo-4-t-butyl-2',6'-bis(p-iodophenyl)-[1,1':4',1]terphenyl (957788-17-9) + 3-(trimethylsilyl)phenylboronic acid (177171-16-3) → 1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene (1609257-11-5) + 1-(4-tert-butylphenyl)-3,4,5-tris(4-(3-trimethylsilylphenyl)phenyl)benzene (1609257-15-9) + C52H53ISi2 (1609257-13-7)

Guidance literature:

With potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; In tetrahydrofuran; at 50 ℃; for 96h; Glovebox; Schlenk technique;

DOI:10.1016/j.tet.2014.04.001

Reference yield: 12.0%

4-bromo-4-t-butyl-2',6'-bis(p-iodophenyl)-[1,1':4',1]terphenyl (957788-17-9) + 3-(trimethylsilyl)phenylboronic acid (177171-16-3) → 2-(4-bromophenyl)-5-(4-tert-butylphenyl)-1-(4-iodophenyl)-3-(4-(3-trimethylsilylphenyl)phenyl)benzene (1609257-14-8) + 1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene (1609257-11-5) + 1-(4-tert-butylphenyl)-3,4,5-tris(4-(3-trimethylsilylphenyl)phenyl)benzene (1609257-15-9) + C52H53ISi2 (1609257-13-7)

Guidance literature:

With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; potassium hydroxide; In tetrahydrofuran; at 60 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.tet.2014.04.001

Reference yield: 2.0%

4-bromo-4-t-butyl-2',6'-bis(p-iodophenyl)-[1,1':4',1]terphenyl (957788-17-9) + 3-(trimethylsilyl)phenylboronic acid (177171-16-3) → 2-(4-bromophenyl)-5-(4-tert-butylphenyl)-1-(4-iodophenyl)-3-(4-(3-trimethylsilylphenyl)phenyl)benzene (1609257-14-8) + 1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-tri-methylsilylphenyl)phenyl)benzene (1609257-11-5) + 1-(4-tert-butylphenyl)-3,4,5-tris(4-(3-trimethylsilylphenyl)phenyl)benzene (1609257-15-9)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In tetrahydrofuran; water; at 60 ℃; for 96h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.tet.2014.04.001

upstream raw materials:

4-bromo-4-t-butyl-2',6'-bis(p-iodophenyl)-[1,1':4',1]terphenyl

3-(trimethylsilyl)phenylboronic acid

Downstream raw materials:

1-(4-bromophenyl)-4-(4-tert-butylphenyl)-2,6-bis(4-(3-iodophenyl)phenyl)benzene