(2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate

Base Information

Chemical Name:(2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate
CAS No.:73127-51-2
Molecular Formula:C₂₉H₄₂O₄S
Molecular Weight:486.716
Hs Code.:

Synonyms:(2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate

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Chemical Property of (2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate

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Technology Process of (2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate

There total 7 articles about (2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 37905-04-7
(2E,6E)-8-bromo-3,7-dimethylocta-2,6-dienyl acetate

: 53254-60-7
3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene

: 73127-51-2
(2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at -5 ℃; for 16h;
DOI:10.1002/jlcr.3083

Reference yield: 71.0%

: 73127-51-2
(2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate

Guidance literature:

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 73127-51-2
(2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate

Guidance literature:: Multi-step reaction with 4 steps

1: 44 percent / SeO₂ / aq. ethanol / 9 h / Heating

2: 72 percent / NaBH₄ / methanol / 5 h / -10 °C

3: 94 percent / PBr₃, pyridine / diethyl ether / 6 h / 0 °C

4: 1.) n-BuLi / 1.) THF, HMPA, hexane, -78 deg C, 1.5 h, 2.) 6 h

With pyridine; sodium tetrahydroborate; n-butyllithium; selenium(IV) oxide; phosphorus tribromide; In methanol; diethyl ether; ethanol;
DOI:10.1039/P19810000761