53254-60-7

Basic information

• Product Name: Geranyl-p-TolylSulfone
• Synonyms: (E)-1-((3,7-dimethylocta-2,6-dien-1-yl)sulfonyl)-4-methylbenzene;(E)-1-((3,7-dimethylocta-2,6-dien-1-yl)sulfonyl)-4-methylbenzene(WXC06063)
• CAS NO: 53254-60-7
• Molecular Formula: C₁₇H₂₄O₂S
• Molecular Weight: 292.44
• Mol File: 53254-60-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 443.16°C at 760 mmHg
• Flash Point: 254.471°C
• Appearance: /
• Density: 1.034g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.519
• CAS DataBase Reference: Geranyl-p-TolylSulfone(CAS DataBase Reference)
• NIST Chemistry Reference: Geranyl-p-TolylSulfone(53254-60-7)
• EPA Substance Registry System: Geranyl-p-TolylSulfone(53254-60-7)

Safety Data

• Hazardous Substances Data: 53254-60-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C17H24O2S/c1-14(2)6-5-7-15(3)12-13-20(18,19)17-10-8-16(4)9-11-17/h6,8-12H,5,7,13H2,1-4H3/b15-12+

Upstream product

• 141-12-8 neryl acetate 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 106-24-1 Geraniol 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 119306-02-4 geranyl p-toluenesulfinate 
• 72863-23-1 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene 
• 115-95-7 linalool acetate 
• 6138-90-5 trans-geranyl bromide 

Downstream Products

• 53260-09-6 1-methyl-4-((6E,10Z)-2,6,11,15-tetramethyl-hexadeca-2,6,10,14-tetraene-8-sulfonyl)-benzene 
• 303-97-9 ubiquinone-45 
• 445301-15-5 C₂₄H₃₄O₄S 
• 68690-51-7 all-trans-1-benzyloxy-3,7,11,15-tetramethyl-9-p-tolylsulfonyl-2,6,10,14-hexadecatetraene 
• 66958-42-7 1,4-Bis-benzyloxy-2,3-dimethoxy-5-methyl-6-[(2E,6E,10E,14E,18E,22E,26E,30E)-3,7,11,15,19,23,27,31,35-nonamethyl-29-(toluene-4-sulfonyl)-hexatriaconta-2,6,10,14,18,22,26,30,34-nonaenyl]-benzene 
• 70238-24-3 1-((E)-3,7-Dimethyl-6-phenylsulfanyl-octa-2,7-diene-1-sulfonyl)-4-methyl-benzene 
• 70473-45-9 (E)-2,6-Dimethyl-3-phenylsulfanyl-8-(toluene-4-sulfonyl)-oct-6-en-2-ol 
• 114060-22-9 methyl(3E)-4,8-dimethyl-2-(p-tolylsulfonyl)-3,7-nonadienoate 
• 114650-30-5 1-[(1S,2R,3R)-2-((E)-2,6-Dimethyl-hepta-1,5-dienyl)-3-(1,5-dimethyl-hex-4-enyl)-cyclopropanesulfonyl]-4-methyl-benzene 
• 114650-30-5 1-[(1S,2S,3R)-2-((E)-2,6-Dimethyl-hepta-1,5-dienyl)-3-(1,5-dimethyl-hex-4-enyl)-cyclopropanesulfonyl]-4-methyl-benzene 
• 3185-99-7 Methyl p-tolyl sulfone 
• 83110-39-8 (2E)-6-chloro-3,7-dimethyl-1-(p-tolylsulfonyl)-2,7-octadiene 
• 114060-23-0 (2E)-6,7-epoxy-3,7-dimethyl-1-(p-tolylsulfonyl)-2-octene 
• 94852-98-9 (2E,6E)-2,6-Dimethyl-8-(toluene-4-sulfonyl)-octa-2,6-dienal 

Relevant articles and documents

SYNTHESES A L'AIDE DE SULFONES. XXIII. SUR LA SELECTIVITE DE LA SYNTHESE DES DULFONES ALLYLIQUES

The role of the palladium ligands on the yield and regioselectivity of the reaction of conjugated dienes with arenesulphinic acids (or of allylic acetates with sodium arenesulphinates) has been investigated.Arenesulphinic acids catalyse the isomerisation of allylic sulphones.

Synthesis of SHIP1-activating analogs of the sponge meroterpenoid pelorol

Two biomimetic approaches have been used to synthesize analogs of the SHIP1-activating sponge meroterpenoid pelorol (1). One approach started from the chiral pool plant natural product sclareolide, which has the same absolute configuration as pelorol. The

Palladium-Catalyzed Allylic Sulfinate-Sulfone Rearrangements

Upon treatment with a zero-valent palladium catalyst, tetrakis(triphenylphosphine)palladium, in tetrahydrofuran under mild conditions allylic p-toluenesulfinates underwent α- or γ-rearrangements of the sulfonyl group via ionic intermediates to give allylic sulfones.The regiochemistry of the rearrangements depends on the character of the intermediary allylic cationic carbons generated and the steric hindrance involved therein.Keywords - allylic sulfinate; allylic sulfone; palladium catalyst; sulfinate-sulfone rearrangement; regiochemistry; tetrakis(triphenylphosphine)palladium.