Geranyl-p-TolylSulfone

Base Information

• Chemical Name: Geranyl-p-TolylSulfone
• CAS No.: 53254-60-7
• Molecular Formula: C17H24O2S
• Molecular Weight: 292.442
• Hs Code.: 2904100000
• Mol file: 53254-60-7.mol

Synonyms:pentoxifylline;1H-Purine-1-pentanoic acid,2,3,6,7-tetrahydro-3,7-dimethyl-2,6-dioxo;CB-Dmx;

Chemical Property of Geranyl-p-TolylSulfone

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.519
• Boiling Point: 443.16°C at 760 mmHg
• Flash Point: 254.471°C
• PSA: 42.52000
• Density: 1.034g/cm³
• LogP: 5.54220

Purity/Quality:

98%Min ^*data from raw suppliers

GERANYL PARA-TOLY SULFONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Geranyl-p-TolylSulfone

There total 9 articles about Geranyl-p-TolylSulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trans-geranyl bromide (6138-90-5) + sodium 4-methylbenzenesulfinate (824-79-3) → 3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene (53254-60-7)

Guidance literature:

With carbon tetrabromide; tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1002/ejoc.201200631

Reference yield: 14.0%

neryl acetate (141-12-8,8022-83-1) + sodium 4-methylbenzenesulfinate (824-79-3) → 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene (72863-23-1) + neryl p-tolyl sulfone (68690-44-8) + 3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene (53254-60-7) + 1-[2-Eth-(E)-ylidene-6-methyl-hept-5-ene-1-sulfonyl]-4-methyl-benzene + 1-Methyl-4-(7-methyl-3-methylene-oct-6-ene-2-sulfonyl)-benzene

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 19 ℃; for 65h; Product distribution; other acetates, other reagents;

DOI:10.1016/S0022-328X(00)85727-7

Reference yield:

sodium 4-methylbenzenesulfinate (824-79-3) + 1-chloro-3,7-dimethylocta-2,6-diene (5389-87-7) → 3,7-dimethyl-1-(p-toluenesulfonyl)-2(E),6-octadiene (53254-60-7)

Guidance literature:

upstream raw materials:

trans-geranyl bromide

sodium 4-methylbenzenesulfinate

neryl acetate

linalool acetate

Downstream raw materials:

1-methyl-4-((6E,10E)-2,6,11,15-tetramethyl-hexadeca-2,6,10,14-tetraene-8-sulfonyl)-benzene

1-methyl-4-((6E,10Z)-2,6,11,15-tetramethyl-hexadeca-2,6,10,14-tetraene-8-sulfonyl)-benzene

C₅₁H₆₈O₆S₃

C₆₈H₉₀O₈S₄