diiron

Base Information

• Chemical Name: diiron
• CAS No.: 12596-01-9
• Molecular Formula: Fe₂
• Molecular Weight: 111.694
• Mol file: 12596-01-9.mol

Synonyms:diiron

Chemical Property of diiron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diiron

There total 3 articles about diiron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diiron-ethylene (98778-48-4) → diiron (12596-01-9) + ethene (74-85-1)

Guidance literature:

In solid matrix; Irradiation (UV/VIS); Fe2(C2H4) was photolyzed in a solid Ar matrix with visible light (λ > 500 nm); IR spectral data;

DOI:10.1021/ja00311a054

Reference yield:

iron pentacarbonyl (13463-40-6,37220-42-1) → diiron (12596-01-9) + iron (7439-89-6)

Guidance literature:

With cis-Octadecenoic acid; In neat (no solvent); thermal decomp. of Fe(CO)5 in the presence of oleic acid and a small amount of trioctylphosphine oxide with the Fe:acid molar ratio fixed at 1:2.5, 180°C, 130°C grouth temp.; crystals were washed with anhydrous methanol; powder X-ray diffraction;

DOI:10.1021/ja044419r

Reference yield:

Fe3Fe(1+) → diiron (12596-01-9) + Fe2Fe(1+) + ferric + iron dimer cation (61674-68-8) + iron (7439-89-6)

Guidance literature:

With Xe; laser vaporization, condensation by helium, supersonic expansion, collision-induced dissoziation, further products: Fe(1+); ion beam mass spectrometry;

upstream raw materials:

iron pentacarbonyl

diiron-ethylene