(Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

Base Information

Chemical Name:(Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene
CAS No.:1270942-77-2
Molecular Formula:C₁₆H₂₁BrO₂
Molecular Weight:325.246
Hs Code.:

Synonyms:(Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

Suppliers and Price of (Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

There total 1 articles about (Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6737-11-7
2-acetoxy-3-butene

: 84695-30-7
(Z)-3-bromo-2-methylprop-2-ene-1-ol

: 824-94-2
p-methoxybenzyl chloride

: 1270942-77-2
(Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

Guidance literature:: 2-acetoxy-3-butene; (Z)-3-bromo-2-methylprop-2-ene-1-ol; With C₄₉H₃₅IrN₂O₈P₂; water; sodium carbonate; In tetrahydrofuran; at 70 ℃; for 144h; Inert atmosphere; Sealed tube;

With di-isopropyl azodicarboxylate; N-ethyl-N,N-diisopropylamine; triphenylphosphine; 4-nitro-benzoic acid; In tetrahydrofuran; at 0 ℃; for 3h; Inert atmosphere;

p-methoxybenzyl chloride; Further stages;
DOI:10.1021/ol200160p

Reference yield: 97.0%

: 1270942-77-2
(Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

: 1270942-78-3
(3S,4R,5Z)-6-bromo-4-(4-methoxybenzyloxy)-3,5-dimethylhex-5-ene-1,2-diol

Guidance literature:: With osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; In dichloromethane; at 25 ℃; for 4h; optical yield given as %de;
DOI:10.1021/ol200160p

Reference yield:

: 1270942-77-2
(Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

: 1270942-88-5
4-[(2R,3R,4Z)-5-bromo-3-(4-methoxybenzyloxy)-4-methylpent-4-en-2-yl]-2,2-dime-thyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 2 steps

1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 25 °C

2: pyridinium p-toluenesulfonate / dichloromethane / 17 h / 25 °C / Inert atmosphere

With osmium(VIII) oxide; water; pyridinium p-toluenesulfonate; 4-methylmorpholine N-oxide; In dichloromethane;
DOI:10.1021/ol200160p