(Z)-2-Methyl-3-bromo-2-propene-1-ol

Base Information

Chemical Name:(Z)-2-Methyl-3-bromo-2-propene-1-ol
CAS No.:84695-30-7
Molecular Formula:C₄H₇BrO
Molecular Weight:151.003
Hs Code.:
DSSTox Substance ID:DTXSID301294893
Nikkaji Number:J2.937.924F

Synonyms:DTXSID301294893;(2Z)-3-Bromo-2-methyl-2-propen-1-ol;(Z)-2-Methyl-3-bromo-2-propene-1-ol;84695-30-7

Suppliers and Price of (Z)-2-Methyl-3-bromo-2-propene-1-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (Z)-2-Methyl-3-bromo-2-propene-1-ol

Chemical Property:

XLogP3:1.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:149.96803
Heavy Atom Count:6
Complexity:58.6

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=CBr)CO
Isomeric SMILES:C/C(=C/Br)/CO

Technology Process of (Z)-2-Methyl-3-bromo-2-propene-1-ol

There total 1 articles about (Z)-2-Methyl-3-bromo-2-propene-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 35911-17-2
1,3-dibromo-2-methylpropene

: 84695-30-7
(Z)-3-bromo-2-methylprop-2-ene-1-ol

: 84695-29-4
(E)-3-bromo-2-methyl-prop-2-en-1-ol

Guidance literature:: With potassium carbonate; In water; at 80 ℃; for 18h;
DOI:10.1021/jo00155a005

Reference yield:

: 6737-11-7
2-acetoxy-3-butene

: 84695-30-7
(Z)-3-bromo-2-methylprop-2-ene-1-ol

: 824-94-2
p-methoxybenzyl chloride

: 1270942-77-2
(Z,3R,4S)-1-bromo-3-(4-methoxybenzyloxy)-2,4-dimethylhexa-1,5-diene

Guidance literature:: 2-acetoxy-3-butene; (Z)-3-bromo-2-methylprop-2-ene-1-ol; With C₄₉H₃₅IrN₂O₈P₂; water; sodium carbonate; In tetrahydrofuran; at 70 ℃; for 144h; Inert atmosphere; Sealed tube;

With di-isopropyl azodicarboxylate; N-ethyl-N,N-diisopropylamine; triphenylphosphine; 4-nitro-benzoic acid; In tetrahydrofuran; at 0 ℃; for 3h; Inert atmosphere;

p-methoxybenzyl chloride; Further stages;
DOI:10.1021/ol200160p

Reference yield:

: 6737-11-7
2-acetoxy-3-butene

: 84695-30-7
(Z)-3-bromo-2-methylprop-2-ene-1-ol

: 62-23-7
4-nitro-benzoic acid

: 1270942-75-0
(3R,4S,Z)-1-bromo-2,4-dimethylhexa-1,5-dien-3-yl 4-nitrobenzoate

: C₁₅H₁₆BrNO₄

Guidance literature:: 2-acetoxy-3-butene; (Z)-3-bromo-2-methylprop-2-ene-1-ol; With C₄₉H₃₅IrN₂O₈P₂; water; sodium carbonate; In tetrahydrofuran; at 70 ℃; for 144h; Inert atmosphere; Sealed tube;

4-nitro-benzoic acid; With di-isopropyl azodicarboxylate; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; at 0 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ol200160p